Abstract:Ultra‐long‐life (at least 10 000 cycles) lithium‐ion batteries are very effective for stationary energy‐storage applications. However, even “zero‐strain” materials with small unit‐cell‐volume changes of <1% cannot last for ultra‐long cycles due to gradually accumulated intracrystal strain/stress. Here, Li[Li0.2Cr0.4Ti1.4]O4 is explored as the first absolutely‐zero‐expansion material with unit‐cell‐volume variations of zero during Li+ storage. Its absolutely‐zero‐expansion mechanism is intensively studied, r… Show more
“…Figure g provides a comprehensive comparison of the zero-strain anode materials’ performances from the perspectives of cycle numbers, current density, and discharge capacity. − To the best of our knowledge, LAO exhibits the best cycling stability under a current density of 5000 mA g –1 in the field of zero-strain anode materials. It also boasts the highest capacity under high current conditions, even without any modifications.…”
At present, graphite is a widely used anode material in commercial lithium-ion batteries for its low cost, but the large volume expansion (about 10%) after fully lithiated makes the material prone to cracking and even surface stripping in the cycle. Therefore, the development of zero-strain anode materials (volume change <1%) is of great significance. LiAl 5 O 8 is a zero-strain insertion anode material with a high theoretical specific capacity. However, the Li + storage mechanism remains unclear, and the cycle life as well as fast-charging capability need to be greatly improved to meet the practical requirements. In this study, LiAl 5 O 8 nanorods are prepared by utilizing aluminum ethoxide nanowires as a soft template and doped with the Zr element to further improve the Li + diffusion coefficient and electronic conductivity, which in turn improves cycle and rate performances. The Zr-doped LiAl 5 O 8 presents a high reversible capacity of 227.2 mAh g −1 after 20,000 cycles under 5 A g −1 , which significantly outperforms the state-of-the-art anode materials. In addition, the Li + storage mechanisms of LiAl 5 O 8 and Zr-doped LiAl 5 O 8 are clearly clarified with a variety of characterization techniques including nuclear magnetic resonance. This work greatly promotes the practical process of zero-strain insertion anode materials.
“…Figure g provides a comprehensive comparison of the zero-strain anode materials’ performances from the perspectives of cycle numbers, current density, and discharge capacity. − To the best of our knowledge, LAO exhibits the best cycling stability under a current density of 5000 mA g –1 in the field of zero-strain anode materials. It also boasts the highest capacity under high current conditions, even without any modifications.…”
At present, graphite is a widely used anode material in commercial lithium-ion batteries for its low cost, but the large volume expansion (about 10%) after fully lithiated makes the material prone to cracking and even surface stripping in the cycle. Therefore, the development of zero-strain anode materials (volume change <1%) is of great significance. LiAl 5 O 8 is a zero-strain insertion anode material with a high theoretical specific capacity. However, the Li + storage mechanism remains unclear, and the cycle life as well as fast-charging capability need to be greatly improved to meet the practical requirements. In this study, LiAl 5 O 8 nanorods are prepared by utilizing aluminum ethoxide nanowires as a soft template and doped with the Zr element to further improve the Li + diffusion coefficient and electronic conductivity, which in turn improves cycle and rate performances. The Zr-doped LiAl 5 O 8 presents a high reversible capacity of 227.2 mAh g −1 after 20,000 cycles under 5 A g −1 , which significantly outperforms the state-of-the-art anode materials. In addition, the Li + storage mechanisms of LiAl 5 O 8 and Zr-doped LiAl 5 O 8 are clearly clarified with a variety of characterization techniques including nuclear magnetic resonance. This work greatly promotes the practical process of zero-strain insertion anode materials.
Aqueous lithium‐ion batteries (ALIBs) have attracted extensive interest since the safety problems of traditional lithium‐ion batteries are waived. Although the energy density of ALIBs is improved, their rate capability and power density are still poor due to the slow Li+ diffusivity of the existing anode materials, and their cyclic stability is also poor. Here, W7Nb4O31 nanorods with very fast‐ and stable‐charging capability are explored as a new anode material for ALIBs for the first time. This material owns different tetragonal tungsten bronze (TTB) structures together with 4 × 4 ReO3‐type blocks confined by TTB matrices, allowing abundant pentagonal and quadrangular tunnels for Li+ transport. These large‐sized tunnels combine with the large interlayer spacing (≈3.95 Å) not only lead to extremely fast Li+ diffusivity but also small unit‐cell volume variations (maximum 2.1%) during lithiation/delithiation, thereby enabling the LiMn2O4//W7Nb4O31 full cell to possess excellent rate capability with a 50C versus 1C capacity ratio of 68.3%, ultrahigh power density of 9854 W kg–1, and superior cyclic stability with capacity retention of 89.7/66.7/72.0% at 1C/5C/50C over 1000/10 000/10 000 cycles. This comprehensive study demonstrates that the W7Nb4O31 nanorods are highly promising for fast‐ and stable‐charging ALIBs.
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