Absolute viscosity of deuterium oxide (oxygen-18) between 15 and 35.deg.

Wolf, D.; Kudish, A. I.

doi:10.1021/j100581a028

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Determination of the Rotational Correlation Time of Water by Proton NMR Relaxation in H₂¹⁷O and Some Related Results

Lankhorst¹,

Schriever²,

Leyte³

1982

Ber Bunsenges Phys Chem

141

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Analysis of the 1H‐17O dipolar contribution to the proton longitudinal relaxation rate in 17O‐enriched water yields a correlation time for re‐orientation of the O–H vector τrOH = (1.71 ± 0.07) ps in H2O at 25 °C. This result is insensitive to uncertainties in the calculated intermolecular relaxation contribution. From 1H, D, and 17O relaxation rates in H2O/D2O mixtures deuterium isotope effects on the correlation times were estimated. The quadrupole coupling constants of D and 17O in liquid water were determined.

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Determination of the Rotational Correlation Time of Water by Proton NMR Relaxation in H₂¹⁷O and Some Related Results

Lankhorst¹,

Schriever²,

Leyte³

1982

Ber Bunsenges Phys Chem

141

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show abstract

SEDNTERP: a calculation and database utility to aid interpretation of analytical ultracentrifugation and light scattering data

Philo

2023

Eur Biophys J

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New International Formulation for the Viscosity of Heavy Water

Assael

Monogenidou

Huber³

et al. 2021

Journal of Physical and Chemical Reference Data

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The International Association for the Properties of Water and Steam has recently adopted a new formulation for the thermodynamic properties of heavy water. This manuscript describes the development of a new formulation for the viscosity of heavy water that is consistent with the new equation of state and is valid for fluid states up to 775 K and 960 MPa with uncertainties ranging from 1% to 5% depending on the state point. Comparisons with experimental data and with a previous viscosity formulation are presented. The new formulation contains terms for the enhancement of viscosity in a small region near the critical point that were not included in previous formulations. The new formulation is applicable over a wider range of conditions than previous correlations.

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Absolute viscosity of deuterium oxide (oxygen-18) between 15 and 35.deg.

Cited by 4 publications

References 0 publications

Determination of the Rotational Correlation Time of Water by Proton NMR Relaxation in H₂¹⁷O and Some Related Results

Determination of the Rotational Correlation Time of Water by Proton NMR Relaxation in H₂¹⁷O and Some Related Results

SEDNTERP: a calculation and database utility to aid interpretation of analytical ultracentrifugation and light scattering data

New International Formulation for the Viscosity of Heavy Water

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Absolute viscosity of deuterium oxide (oxygen-18) between 15 and 35.deg.

Cited by 4 publications

References 0 publications

Determination of the Rotational Correlation Time of Water by Proton NMR Relaxation in H217O and Some Related Results

Determination of the Rotational Correlation Time of Water by Proton NMR Relaxation in H217O and Some Related Results

SEDNTERP: a calculation and database utility to aid interpretation of analytical ultracentrifugation and light scattering data

New International Formulation for the Viscosity of Heavy Water

Contact Info

Product

Resources

About

Determination of the Rotational Correlation Time of Water by Proton NMR Relaxation in H₂¹⁷O and Some Related Results

Determination of the Rotational Correlation Time of Water by Proton NMR Relaxation in H₂¹⁷O and Some Related Results