Abraham model enthalpy of solvation correlations for solutes dissolved in dimethyl carbonate and diethyl carbonate

Calculation of Abraham model L-descriptor and standard molar enthalpies of vaporization and sublimation for C9 - C26 mono-alkyl alkanes and polymethyl alkanes

“…Abraham model correlations are available for predicting the enthalpies of solvation of solutes in several common organic solvents as well. [45][46][47][48][49][50][51][52][53][54][55] Each of our published Abraham model correlations uses the same set of solute descriptors for a given compound, irrespective of the property being predicted.…”

“…A complete set of solute descriptors enables one to estimate a large number of physicochemical and thermodynamic properties using published Abraham model correlations. To date we have reported mathematical expressions for predicting log K and log P values for solutes dissolved in both traditional molecular organic solvents [39][40][41][42][43] and ionic liquid solvents, [64][65][66][67][68][69][70][71][72][73] molar solubility ratios, [39][40][41][42][43] blood-to-body tissue/fluid partition coefficients, [74][75][76][77][78] Draize scores and eye irritation thresholds, [79][80][81] enthalpies of solvation, [45][46][47][48][49][50][51][52][53][54][55] lethal median concentrations of organic compounds towards fish and other aquatic organisms, [82][83][84][85] nasal pungency, 79,[86]…”

Effect of halogen substitution on the enthalpies of solvation and hydrogen bonding of organic solutes in chlorobenzene and 1,2-dichlorobenzene derived using multi-parameter correlations

“…This study continues our combined experimental and theoretical examination of gas-toorganic solvent transfer processes for nonelectrolyte solutes [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19]. Such processes govern chemical separations by gas-liquid chromatography, measurement of solubilities and activity coefficients by inert-gas stripping methods, and the removal and pre-concentration of volatile organic solutes from aqueous analytical samples using headspace single drop micro-extraction methods.…”

“…The organic solvents included several saturated hydrocarbons [1,2] and aromatic hydrocarbons [1,3,4], chlorinated alkanes [4][5][6], several primary, secondary and tertiary alcohols [7][8][9][10][11], two dialkyl carbonates [12], one alkyl acetate solvent [13], one dialkyl ether [13] and two cyclic ethers [6,8], as well as several miscellaneous organic solvents [9,14,15]. In each case eqns.…”

“…In previous publications [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15] we have developed Abraham model correlations:…”