Abraham model correlations for solute transfer into tributyl phosphate from both water and the gas phase

Abraham model correlations for describing solute transfer into 2-butoxyethanol from both water and the gas phase at 298K

“…The model that we have been using in our studies has been the Abraham solvation parameter model [2,[21][22][23][24][25][26], which allows one to describe solute transfer between two condensed phases (a biphasic aqueous-organic or organic-organic system) or solute transfer to a condensed phase from the vapor phase. During the past five years we have published Abraham model correlations for 11 additional organic solvents (e.g., diisopropyl ether [27], tributyl phosphate [28], 2-hexadecene [29,30], 1,9-decadiene [29,30], sulfolane [31], benzonitrile [32], ethylbenzene [33], o-xylene [34], m-xylene [34], p-xylene [34], 2-ethoxyethanol [35], and propylene glycol [36]) and several ionic liquids [37][38][39][40][41][42][43][44][45][46][47], as well as updating our existing correlations for hexane [48], heptane [48], octane [48], decane [48], isooctane [49], toluene [33], tetrahydrofuran [50], and 1,4-dioxane [50].…”

Abraham model correlations for solute transfer into 2-methoxyethanol from water and from the gas phase

“…To date process coefficients have been published for more than 80 different organic solvents including several alkanes, alkanols, haloalkanes, substituted benzenes, alkyl alkanoates, dialkyl and cyclic ethers, alkanones, and other miscellaneous organic compounds of varying polarity and hydrogen-bonding character [4][5][6][7][8][9]. We are continually reporting process coefficients for additional solvents and partitioning systems.…”

“…We are continually reporting process coefficients for additional solvents and partitioning systems. Coefficients were recently determined for both diisopropyl ether [6] and tributyl phosphate [5].…”

“…The Abraham solvation parameter model [2][3][4][5][6] is one of the more successful approaches used in recent years to describe solute partitioning into and solute solubilities in organic solvent systems. Solute partitioning can be between two condensed phases (a biphasic aqueous-organic or organic-organic system):…”

Abraham model correlations for solute transfer into 2-ethoxyethanol from water and from the gas phase

“…The first ever established C-H · · · ·Y hydrogen-bond involved the participation of the acidic C-H group in the chloroform molecule. To date we have published correlations for describing the solubility and partitioning behavior of solutes into inert solvents (hexane -hexadecane [2,3], cyclohexane [2], methylcyclohexane [2], and isooctane [4]), into several alkylbenzene [2,5,6] and halobenzene [7] solvents, into several aprotic H-bond acceptor solvents (dibutyl ether [2], diethyl ether [2], diisopropyl ether [8], 1,4-dioxane [9], tetrahydrofuran [9], acetone [10], butanone [10], cyclohexanone [10], methyl acetate [11], ethyl acetate [11], butyl acetate [11], tributyl phosphate [12] and dimethyl sulfoxide [2]), and into several protic alcohol solvents (methanol -decanol [2, 13], 2-propanol [2,14], 2-butanol [2,14], 2-methyl-1-propanol [2,14], 2-methyl-2-propanol [2,14], ethylene glycol [2,15] and propylene glycol [16]) that possess both H-bond donor and Hbond acceptor character. In total we have reported correlations for more than 80 common organic solvents [2], for more than 35 different ionic liquids , and for aqueous micellar sodium dodecylsulfate [38] and aqueous micellar cetyltrimethylammonium bromide [39] solvent media.…”