Ab initio conformational analysis of 1,5-dithiacyclooctane, 1,5-diselenacyclooctane, and 1,5-ditelluracyclooctane

This account summarizes representative contributions of Prof. Naomichi Furukawa to the field of heteroatom chemistry. Ligand‐coupling reactions (LCRs) and ligand‐exchange reactions (LERs) of chalcogen derivatives were developed from reactions of trivalent chalcogen species with organometallic reagents. Prof. Furukawa has also reported a large number of mono‐ and dicationic compounds generated via transannular and intermolecular interactions. Furthermore, the detection and isolation of hypercoordinated chalcogen species bearing only carbon ligands and an efficient method for the synthesis of thiophene S‐oxides and their reactivity are described.

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Ab initio conformational analysis of 1,5-dithiacyclooctane, 1,5-diselenacyclooctane, and 1,5-ditelluracyclooctane

Cited by 9 publications

References 29 publications

Ab initio molecular orbital study of dications of 1,5-dichalcogenacyclooctanes

Ab initio molecular orbital study of dications of 1,5-dichalcogenacyclooctanes

Conformationally induced electrostatic stabilization (CIES) of persulfoxides. A comparison to homologous sulfoxides

Studies on diverse chemical species derived from chalcogen atoms ~ The Footprint of Professor Naomichi Furukawa in Heteroatom Chemistry ~

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