A2BC-type meso-imidazolylporphyrins – New class of prospective polyfunctional molecules

Nanostructured Aluminum Oxyhydroxide—A Prospective Support for Functional Porphyrin-Based Materials

“…The synthesis of the functionalized A2BC-type porphyrin began w ing meso-formyl porphyrin (Ni-1), which was transformed into Ni-5 i dure (Scheme 1) [43]. The polyaromatic fragment was introduced to t Chart 1.…”

“…The synthesis of the functionalized A 2 BC-type porphyrin began with the corresponding meso-formyl porphyrin (Ni-1), which was transformed into Ni-5 in a multistep proce-dure (Scheme 1) [43]. The polyaromatic fragment was introduced to the porphyrin using the Debus-Radziszewski reaction of Ni-1 with phenantrene-9,10-dione in the presence of an excess of ammonium acetate.…”

“…Nickel(II) 5-formyl-10,20-di(4-butoxyphenyl)porphyrin Ni-1 was prepared following the reported procedure [59]. Porphyrins Ni-2-Ni-5 were prepared from Ni-1 as reported previously [43,60]. The detailed synthetic procedures and spectral characteristics of all compounds used in the study (Figures S1-S24) can be found in ESI.…”