A Water‐Stable Porphyrin‐Based Metal–Organic Framework Active for Visible‐Light Photocatalysis

Fateeva, Alexandra; Chater, Philip A.; Ireland, Christopher P.; Tahir, Asif Ali; Khimyak, Yaroslav Z.; Wiper, Paul V.; Darwent, James R.; Rosseinsky, Matthew J.

doi:10.1002/anie.201202471

Cited by 709 publications

(542 citation statements)

References 48 publications

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“…The similar film of carboxyphenyl porphyrin Co complex-Al-O cluster supplied the same catalytic behavior [26]. Different MOFs based on tetra(4-carboxyphenyl)porphyrin Fe complex-Zr-O cluster can also be selected as catalyst in catalytic conversion from CO 2 to ethylene glycol lactone [27] [33]. Another MOFs of tetra(4-carboxyphenyl)porphyrin Sn complex-W-O cluster possessed multifunctional activity in catalysis [34].…”

Section: Other Close Research On Molecular Assembly and Applications mentioning

confidence: 96%

Assembly of Covalently Inorganic-Organic Hybrid Molecular Framework Based on Porphyrin and Phthalocyanine Derivatives—Sensitizer for Dye Sensitized Solar Cells

Lin¹,

Wu²,

Tong³

et al. 2018

OJIC

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The research on sensitizer for dye sensitized solar cells based on (metallo)porphyrin/phthalocyanine materials were reviewed, and experimental design and assembly method were advised. Latest progress and research status of sensitizer dyes based on metalloporphyrins applied in dye sensitized solar cells was summarized. The preparation and construction of sensitizer electrodes and dye sensitized solar cells based on metal organic frameworks (MOFs) of (metallo)porphyrin/phthalocyanine were projected.

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Section: Other Close Research On Molecular Assembly and Applications mentioning

confidence: 96%

Assembly of Covalently Inorganic-Organic Hybrid Molecular Framework Based on Porphyrin and Phthalocyanine Derivatives—Sensitizer for Dye Sensitized Solar Cells

Lin¹,

Wu²,

Tong³

et al. 2018

OJIC

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“…Figure 2 illustrates a schematic overview. In 2012, Fateeva et al [47] presented a porphyrinebased MOF with aluminium nodes. The structure of this Al-MOF is comparable to MIL-60 [48].…”

Section: Mof-photosensitizer Schemes With External Catalystmentioning

confidence: 99%

“…Sacrificial donors (SD) are typically ethylenediaminetetraacetic acid (EDTA) or triethylamine (TEA). In this case, the photosensitizer are porphyrine linkers and Pt-nanoparticles serve as catalyst [47] Fig. 3 MOF with dual functionality.…”

Section: Mofs Containing Both Photosensitizer and Catalystmentioning

confidence: 99%

Photochemical Hydrogen Production with Metal–Organic Frameworks

Pullen

Ott

2016

Top Catal

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Metal-Organic Frameworks (MOFs) have attracted increasing attention for the creation of solid-state platforms for catalysis applications. In this review article, we present strategies to employ MOF-based materials in photochemical hydrogen production. The scope ranges from the incorporation of single functions (catalyst or photosensitizer) to multifunctional MOFs that combine both light-harvesting and catalysis in one scaffold.

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“…[1,2] Porphyrins have good thermal stability and versatile chemical properties, making them candidates for a wide variety of applications such as catalysis, [3,4] solar energy conversion, [5,6] and the development of metal-organic frameworks. [7][8][9] Among the porphyrins, 5,10,15,20-Tetra(4-pyridyl)porphyrin (H2TPyP) is one of the meso-substituted prophyrins that have been widely used in various chemical and photochemical studies. [10,11] It has a strong Soret band at ~420 nm, depending on the precise composition of the molecule and metallocentric ad-atoms, [12] which has enabled new applications such as dye-sensitized solar cells and thin semiconducting layers (e.g.…”

Section: Introductionmentioning

confidence: 99%

Formation of Au and tetrapyridyl porphyrin complexes in superfluid helium

Cheng

Latimer

Spence

et al. 2015

Phys. Chem. Chem. Phys.

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Binary clusters containing a large organic molecule and metal atoms have been formed by the co-addition of 5,10,15,20-Tetra(4-pyridyl)porphyrin (H2TPyP) molecules and gold atoms to superfluid helium nanodroplets, and the resulting complexes were then investigated by electron impact mass spectrometry. In addition to the parent ion H2TPyP yields fragments mainly from pyrrole, pyridine and methylpyridine ions because of the stability of their ring structures. When Au is co-added to the droplets the mass spectra are dominated by H2TPyP fragment ions with one or more Au atoms attached. We also show that by switching the order in which Au and H2TPyP are added to the helium droplets, different types of H2TPyP/Au complexes are clearly evident from the mass spectra. This study suggests a new route for the control over the growth of metal-organic compounds inside superfluid helium nanodroplets.3

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A Water‐Stable Porphyrin‐Based Metal–Organic Framework Active for Visible‐Light Photocatalysis

Cited by 709 publications

References 48 publications

Assembly of Covalently Inorganic-Organic Hybrid Molecular Framework Based on Porphyrin and Phthalocyanine Derivatives—Sensitizer for Dye Sensitized Solar Cells

Assembly of Covalently Inorganic-Organic Hybrid Molecular Framework Based on Porphyrin and Phthalocyanine Derivatives—Sensitizer for Dye Sensitized Solar Cells

Photochemical Hydrogen Production with Metal–Organic Frameworks

Formation of Au and tetrapyridyl porphyrin complexes in superfluid helium

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