Abstract:Reductive metal deposition at the interface between two immiscible electrolyte solutions (ITIES), the oil/water interface, is an attractive methodology to produce metal nanostructures. However, the metals that can be deposited are limited to noble metals; otherwise, water molecules are reduced. Herein, a method to overcome this limitation by utilizing a novel waterfree ITIES between a hydrophilic ionic liquid and oil was introduced. As proof-of-concept experiments, the reductive deposition of zinc, a base meta… Show more
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