Several overcoat materials are applied to a chemically amplified positive X-ray resist (CANT). Although water-soluble materials are preferable in terms of safety and cost, they reduce the resist sensitivity. One reason for this is that moisture originating in the overcoats lessens activity of the catalytic acids needed for chemical amplification. Among the materials investigated, poly(a-methylstyrene) treated with xylene as a solvent most efficiently reduces post-exposure delay effect and withdraws the lithographic performance of CANT.