A unique air-assisted DMSO oxidation pathway for the highly efficient synthesis of 2,5-diformylfuran from 5-hydroxymethylfurfural/fructose

Abstract

A unique air-assisted DMSO oxidation pathway is activated by the co-adsorption of DMSO and O2 on Co-(pyrrolic N–C) pairs of CoNC-MCM.

Electrochemical C3-methylthiolation of imidazopyridines with dimethyl sulfoxide

“…4 So the study on the methylthiolation of organic compounds has aroused great interest among organic chemists. Dimethyl sulfoxide (DMSO), a cheap and readily available solvent, has been used as a reagent in numerous transformations, such as oxidation, 5 methylation, 6 methylenation, 7 methylsulfonylation, 8 etc . It is well known that heterocyclic compounds are a significant part of organic and medicinal chemistry research and the industries.…”