Abstract:The optical band positions and the spin-Hamiltonian parameters (g factors g , g ⊥ , and zero-field splitting parameter D) of alum α-RbAl(SO4)2 · 12H2O:Cr 3+ are calculated by diagonalizing the 120 × 120 complete energy matrix based on the two-spin-orbit-coupling-parameter model. The model takes into account not only the contributions due to the spin-orbit-coupling parameter of central d n ion in the conventional crystal field theory, but also those due to ligands via covalence effect. The calculation indicates… Show more
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