A Unified Approach to (E)- and (Z)-Olefins Enabled by Low-Valent Tungsten Catalysis
Tanner Jankins,
Camille Rubel,
Hang Chi Ho
et al.
Abstract:Achieving regio- and stereoselective formation of products from simple chemical building blocks is one the most important roles of catalysis in organic synthesis. Repositioning an alkene functional group through catalytic alkene isomerization represents a powerful synthetic strategy for preparing valuable alkene products from comparatively simple chemical feedstocks. The utility of this approach, however, hinges on the ability to control the positional and stereoisomerism to access a single product among numer… Show more
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