A two-dimensional cadmium(II) coordination polymer: poly[diaquabis(μ₂-2,4-dichlorophenoxyacetato)cadmium(II)]

Abstract

Key indicatorsSingle-crystal X-ray study T = 295 K Mean (C-C) = 0.004 Å R factor = 0.026 wR factor = 0.067 Data-to-parameter ratio = 17.1 For details of how these key indicators were automatically derived from the article, see

The Synthesis of Zinc(II) and Cadmium(II) 2,4-Dichlorophenoxyacetates in Water–Methanol Environment. Structure and Properties of Polymeric [Zn(2,4-D)2(MeOH)2] n and [Cd(2,4-D)2(H2O)2] n

“…Selected interatomic bond distances and angles are listed in Table 2, and geometrical parameters of intermolecular interactions are listed in Table 3. The determined structural parameters of 2 were consistent with previously reported ones [18].…”

“…In recent years there is observed an increasing interest on 2,4-D-H salts and coordination compounds, including salts of transition metals such as Cd(II) [12,18,19], Mn(II) [20][21][22], Zn(II) [23,24], Mg(II) [21], Ni(II) [25], Ag(I) [26], Fe(II) [27], Cu(II) [28], alkaline metals and p block elements such as Ba(II) [29], Ca(II) [30], Pb(II) [12] and lanthanides like Gd [31], Nd [32] and Eu [33]. Several mixed-ligand coordination compounds with 2, 4-dichlorophenoxyacetate (2,4-D) and other ligands (e.g.…”

Two cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures

“…Examples of cadmium coordination polymers with carboxylate ligands and that exhibit two-dimensional sheet structures have been reported (Li et al, 2014;Gao et al, 2004;Chen & Zhang, 2014;Zhang et al, 2007;Liu & Xu, 2005;Song et al, 2006;Kong et al, 2008a,b;Xu et al, 2013;Zhuo et al, 2006).…”

Influence of cadmium(II) source upon the formation of a discrete monomer [Cd(κ2-OC(O) Bu)2(H2O)2] and a trinuclear heterobimetallic 1D CP, {Na2[Cd(μ5-κ3:κ3-OAc)(μ3-κ2:κ3-OC(O) Bu)(μ3-κ1:κ2-OC(O) Bu)2]·2 BuC(O)OH}∞

“…Cadmium(II) carboxylates are useful precursors for discrete Lewis base coordinated cadmium(II) carboxylate complexes, coordination polymers (CPs), metal organic frameworks (MOFs) and cadmium chalcogenides. Cadmium(II) monocarboxylate complexes are known to exist as discrete monomers, dimers, aggregates formed through covalent coordinate bond depending upon the substituent at the carboxylate ligand [1][2][3][4][5][6]. Mixed cadmium(II) mono carboxylate complexes are also known to exist as an aggregate formed through covalent coordinate bond [7].…”