Electronic structures near the Fermi level of
polymer/1T-LixTaS2
layered nanocomposites have been studied by tunnelling spectroscopy.
Polymer/1T-LixTaS2
layered nanocomposites were synthesized by using the exfoliation–adsorption technique. Single crystals
of 1T-TaS2
were used as host materials. Poly(ethylene oxide) (PEO) and poly(ethylenimine)
(PEI) with different molecular weights were adopted as guest intercalants.
Powder x-ray diffraction patterns showed that all samples of the
polymer/1T-LixTaS2
layered nanocomposites contain organic polymer between all individual
1T-TaS2 sheets.
Although 1T-TaS2
single crystal is well known to show quite unique temperature dependences of
the resistivity due to the charge density wave (CDW), the resistivities of all
polymer/1T-LixTaS2
nanocomposites showed semiconductor-like temperature dependences. The tunnelling spectra of
polymer/1T-LixTaS2
nanocomposites revealed that the CDW gap disappears in the density of states near the Fermi level
of polymer/1T-LixTaS2
nanocomposites and their electronic structures show a metallic behaviour.