The comparatively high coercive field in Hf0.5Zr0.5O2 (HZO) and other HfO2-based
ferroelectric
thin films leads to two critical challenges for their application
in embedded ferroelectric memory: high operating voltage due to a
large thickness-field product and poor endurance due to the high operating
field close to the breakdown field. In this study, we demonstrate
that the thickness scaling of ferroelectric HZO down to 4 nm is a
promising approach to overcome these challenges. As the coercive voltage
scales down almost linearly with the film thickness, the operating
voltage of 4 nm HZO is reduced to 0.6 V for one-shot operation and
1.2 V for stable memory operation, which is in the voltage range compatible
with scaled silicon technologies. Furthermore, it is found that the
breakdown field is substantially improved in thinner HZO since the
breakdown mechanism is dominated by the stress voltage, not the stress
field, resulting in improved cycle-to-breakdown by more than 4 orders
of magnitude when thinning from 9.5 to 4 nm. We identify two concerns
accompanying thickness scaling: the increase in crystallization temperature
and the pinched hysteresis behavior, which can be addressed by carefully
preparing temperature-thickness mapping and applying strong-field
wake-up cycling, respectively. Our optimal 4 nm-thick HZO ferroelectric
capacitor exhibits an operating voltage of 1.2 V with over 10 year
data retention and 1012 endurance cycles at 100 kHz, which
can be further improved to more than 1014 with a smaller
capacitor size and higher operating frequency.