1998
DOI: 10.1107/s0108270197014911
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A Topologically Novel Binuclear Silver Complex of Di-2-pyridyl Sulfide

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Cited by 11 publications
(8 citation statements)
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“…Such a substructure is also present in the silver nitrate complex of di-2-pyridyl sulfide. 12 Fused to this macrocycle is a twenty-membered centrosymmetric dinuclear ring. Again, the ring is formed by coordination of a pyridine nitrogen and a sulfur atom to each of two silver atoms.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…Such a substructure is also present in the silver nitrate complex of di-2-pyridyl sulfide. 12 Fused to this macrocycle is a twenty-membered centrosymmetric dinuclear ring. Again, the ring is formed by coordination of a pyridine nitrogen and a sulfur atom to each of two silver atoms.…”
Section: Resultsmentioning
confidence: 99%
“…11 Furthermore, we have recently shown that reaction of silver nitrate with di-2-pyridyl sulfide, a ligand that normally acts as a N,N-bidentate chelating ligand, results in the formation of a novel binuclear complex in which the ligand co-ordinates in an N,N,S-tridentate bridging mode to form a structure with the same topology as those of the well studied organic photodimers of anthracene. 12 The study of such assembly processes can provide useful information for use in the rapidly expanding area of crystal engineering. 13 We now report the preparation of four new bridging ligands that contain 2-pyridylsulfanyl groups attached to xylylene cores, and the synthesis and crystal structures of their respective complexes with silver() nitrate.…”
Section: Introductionmentioning
confidence: 99%
“…When dps is connected to the metal atom as a chelate ligand, a six-membered ring in boat conformation is formed, differently from its rigid analogues 2,2′-bipyridine that generates a pentacyclic chelate in a planar arragement. In addition, in some cases dps can act as tridentate ligand in a N,N,S-coordination mode involving metal-sulfur interactions (Anderson & Steel, 1998). …”
Section: Methodsmentioning
confidence: 99%
“…For related literature, see: Anderson & Steel (1998); Bhosekar et al (2007); Kondo et al (1995); Nicolò et al (1996); Teles et al (1999); Tresoldi et al (1991Tresoldi et al ( , 1992.…”
Section: Related Literaturementioning
confidence: 99%
“…Reaction of a related ligand di-2-pyridyl sulfide with Ag(I) produces a binuclear dimer containing two ligands. 5 This work would suggest 1 may not be ideally suited to forming mononuclear Ag(I) complexes. Electrospray mass spectrometry under normal operating conditions showed parent ions with appropriate isotope patterns for {[Ag 2 (1) 2 ]PF 6 } + at m/z 790.8 and [Ag 2 (1) 2 ] 2+ at m/z 323.5.…”
mentioning
confidence: 96%