In the visible range at blue 455 nm, 482 nm, and red 670 nm under upconversion pumping at a wavelength of 1064 nm, spectroscopic characteristics, and transition rates in Tm3+ doped 0.53 ZrF4, 0.2 BaF2, 0.04 LaF3, and 0.03 AlF3 and 0.2 NaF (ZBLAN) glass matrix are described. The Judd-Ofelt theory is applied to calculate the contributions from electric and magnetic dipoles to the optical intensity parameters (Ωt), which are found to be as follows: Ω2 =1.4703± 0.0675, Ω4=0.7477± 0.0536, Ω6=0.6202± 0.0212. For transitions originating from the 1D2, 1G4, 2F2, 3F3, and 3F4 levels, branching ratios (β), radiative lifetimes (rad in ms units), and transition probabilities (in s-1) have been calculated. Additionally, we evaluated the optical gain at 455 nm, 467 nm and 670 nm, as well as the absorption/emission cross sections for the three visible transitions. According to the obtained results, the transition at 455 nm (1D23F4) had the largest emission cross section values compared to transitions at 482 nm (1G43H6) and 670 nm (3F23H6). Furthermore, the transition probability.is theoretically calculated for the ultraviolet (UV) range 172–283.8 nm. A good agreement is found between the calculations and the measurements for the visible range.