A three-dimensional highly stable Zn(II) coordination polymer based on 1,4-benzeneditetrazolate (H2BDT): Synthesis, crystal structure, and luminescent properties

Deng, Jing; Yuan, Xiaolin; Guang-quan, Mei

doi:10.1016/j.inoche.2010.09.023

Cited by 24 publications

(9 citation statements)

References 49 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…For the synthesis of 5-substituted 1H-tetrazoles, see: Ostrovskii et al (2008); Saikia & Phukan (2009); Nasrollahzadeh et al (2009); Teimouri & Najafi Chermahini (2011). For related structures, see: Li et al (2008); Hu et al (2009); Xu et al (2010); Deng et al (2010).…”

Section: Related Literaturementioning

confidence: 99%

4-[4-(1H-Tetrazol-5-yl)phenoxy]benzaldehyde

Lü

et al. 2011

Acta Cryst E

View full text Add to dashboard Cite

The asymmetric unit of the title compound, C14H10N4O2, contains two independent molecules with similar structures. In one molecule, the tetrazole ring is oriented at dihedral angles of 17.71 (16) and 57.13 (17)°, respectively, to the central benzene ring and the terminal benzene ring; in the other molecule, the corresponding dihedral angles are 16.46 (18) and 75.87 (18)°. Intermolecular N—H⋯N hydrogen bonds and weak C—H⋯O and C—H⋯N hydrogen bonds occur in the crystal structure.

show abstract

Section: Related Literaturementioning

confidence: 99%

4-[4-(1H-Tetrazol-5-yl)phenoxy]benzaldehyde

Lü

et al. 2011

Acta Cryst E

View full text Add to dashboard Cite

show abstract

“…Coordination networks are important due to their welldefined architecture [1][2][3][4][5][6][7][8][9][10] and applications in sorption, 11,12 separation, 13,14 sensing, [15][16][17] ion-exchange and transport, 18,19 proton conduction, [20][21][22] optics, [23][24][25][26][27] magnetism, 28,29 devices, 30,31 and catalysis. [32][33][34][35][36] Due to their ordered architecture, porosity, and stability; such materials have shown significant results as the heterogeneous catalysts for assorted organic transformations.…”

Section: Introductionmentioning

confidence: 99%

Three-Dimensional Heterometallic Coordination Networks: Syntheses, Crystal Structures, Topologies, and Heterogeneous Catalysis

Srivastava

Aggarwal

Gupta

2015

Crystal Growth & Design

View full text Add to dashboard Cite

This work presents the synthesis of {Co 3+ -Zn 2+ } and {Co 3+ -Cd 2+ } heterometallic coordination networks. These networks are originated from two unique Co 3+ -based metalloligands containing appended arylcarboxylic acid groups at the strategically placed positions. Such appended arylcarboxylate groups coordinate the secondary metal ions, Zn 2+ and Cd 2+ , to afford distinct three-dimensional networks. All four networks display orderly arrangement of secondary metal ions and unique network topologies including an unprecedented one. These networks have been shown to act as the heterogeneous and reusable catalysts for the Knoevenagel condensation reactions and cyanation reactions of assorted aldehydes. Cyanation reactions nicely demonstrate the substrate size-exclusion catalysis.

show abstract

“…[1][2][3][4][5][6][7][8] Recently, we studied metal complexes with a multidentate ligand, N,N,N¢,N¢-tetrakis(3,5-dimethyl-1-pyrazolyl)methyl-1,4-phenylenediamine (tpmp), having the 1,4-phenylenediamine moiety, and isolated a dinuclear cobalt complex from a reaction of cobalt(II) chloride and tpmp consisting of two tetrahedral cobalt(II) atoms with two pyrazolato-nitrogen atoms of tpmp and two chloride atoms. 6 In this study, we tried to extend this work to reactions with other metal salts, such as cobalt(II) acetate and nickel(II) acetate.…”

mentioning

confidence: 99%

Tetranuclear Nickel(II) and Cobalt(II) Complexes with 3,5-Dimethyl-1-pyrazolylmethanolato and Acetato Bridges Having a Cubane Core

Lim¹,

Kim²,

Do³

et al. 2015

X-ray Structure Analysis Online

View full text Add to dashboard Cite

There have been considerable interest in the coordination chemistry of metal complexes with pyrazole and their derivatives owing to diverse coordination modes and relevance to a biological-active metal center with imidazole-like ligands. [1][2][3][4][5][6][7][8] Recently, we studied metal complexes with a multidentate ligand, N,N,N¢,N¢-tetrakis(3,5-dimethyl-1-pyrazolyl)methyl-1,4-phenylenediamine (tpmp), having the 1,4-phenylenediamine moiety, and isolated a dinuclear cobalt complex from a reaction of cobalt(II) chloride and tpmp consisting of two tetrahedral cobalt(II) atoms with two pyrazolato-nitrogen atoms of tpmp and two chloride atoms. 6 In this study, we tried to extend this work to reactions with other metal salts, such as cobalt(II) acetate and nickel(II) acetate. We found totally different products with 3,5-dimethyl-1-pyrazolyl)methanolato (dmpm -), as shown in Fig

show abstract

A three-dimensional highly stable Zn(II) coordination polymer based on 1,4-benzeneditetrazolate (H2BDT): Synthesis, crystal structure, and luminescent properties

Cited by 24 publications

References 49 publications

4-[4-(1H-Tetrazol-5-yl)phenoxy]benzaldehyde

4-[4-(1H-Tetrazol-5-yl)phenoxy]benzaldehyde

Three-Dimensional Heterometallic Coordination Networks: Syntheses, Crystal Structures, Topologies, and Heterogeneous Catalysis

Tetranuclear Nickel(II) and Cobalt(II) Complexes with 3,5-Dimethyl-1-pyrazolylmethanolato and Acetato Bridges Having a Cubane Core

Contact Info

Product

Resources

About