Formation of an extended CoSi2 thin nanohexagons array coherently buried in silicon single crystal Appl. Phys. Lett. 100, 063116 (2012) Magnetic behaviour of Ni0.4Zn0.6Co0.1Fe1.9O4 spinel nano-ferrite J. Appl. Phys. 111, 07A305 (2012) Fabrication of Fe@mSiO2 nanowires with large remanence and low cytotoxicity for targeted drug delivery J. Appl. Phys. 111, 07B302 (2012) Fabrication of nanoscale glass fibers by electrospinning Appl. Phys. Lett. 100, 063114 (2012) ZnO/Si arrays decorated by Au nanoparticles for surface-enhanced Raman scattering study J. Appl. Phys. 111, 033104 (2012) Additional information on J. Appl. Phys. A useful synthesis technique, shock synthesis of bulk nanomaterials from nanopowders, is explored here with molecular dynamics simulations. We choose nanoporous Cu ($11 nm in grain size and 6% porosity) as a representative system, and perform consolidation and spallation simulations. The spallation simulations characterize the consolidated nanopowders in terms of spall strength and damage mechanisms. The impactor is full density Cu, and the impact velocity (u i ) ranges from 0.2 to 2 km s À1 . We present detailed analysis of consolidation and spallation processes, including atomic-level structure and wave propagation features. The critical values of u i are identified for the onset plasticity at the contact points (0.2 km s À1 ) and complete void collapse (0.5 km s À1 ). Void collapse involves dislocations, lattice rotation, shearing/friction, heating, and microkinetic energy. Plasticity initiated at the contact points and its propagation play a key role in void collapse at low u i , while the pronounced, grain-wise deformation may contribute as well at high u i . The grain structure gives rise to nonplanar shock response at nanometer scales. Bulk nanomaterials from ultrafine nanopowders ($10 nm) can be synthesized with shock waves. For spallation, grain boundary (GB) or GB triple junction damage prevails, while we also observe intragranular voids as a result of GB plasticity.