A Theoretical Analysis of Single Drop Square‐Wave Polarography

Abstract

The peak current response to single drop square‐wave polarography (SDSWP) is developed based on a spherical diffusion model. It is found that the equation originally developed by Ramaley et al. based on a planar diffusion model is only a special case of the generalized model.

Recent Advances and Prospects of Square-Wave Voltammetry

“…The popularity of the technique has been permanently increasing since the seminal work of Osteryoungs [9,10], remarkable theoretical work of Lovrić [11] and contributions of others [12][13][14][15][16][17][18][19][20][21][22][23][24]. Methodological development and application of the technique have been reviewed over the years [25][26][27][28][29][30][31][32][33][34][35][36] and two specialized monographs are exclusively dedicated to SWV [1,37].…”