A switchable sensor and scavenger: detection and removal of fluorinated chemical species by a luminescent metal–organic framework

Abstract

Fluorosis has been regarded as a worldwide disease that seriously diminishes the quality of life through skeletal embrittlement and hepatic damage. Effective detection and removal of fluorinated chemical species such...

Precise Design and Deliberate Tuning of Turn-On Fluorescence in Tetraphenylpyrazine-Based Metal−Organic Frameworks

“…Interestingly, we found that the center pyrazine core twisted into a nonplanar structure, so we can construct two planes, and the twist angle is 21.1° (Figure S5 ). Thus, the pyrazine ring and phenyl arms dihedral angle become 34.8° and 40.9°, respectively, in Tb-TCPP-1 from 20.1° of free H 4 TCPP [ 38 , 50 ] (Figures 3(b) and 3(e) ). On the contrary, so as to match the 12-c Tb 9 cluster in the she net of Tb-TCPP-2, the two N atoms in pyrazine of TCPP 4- are coplanar to other carbon atoms, which are similar with the H 4 TCPB based shp net Y-shp-MOF-5 and the H 4 TCMB based csq net Y-csq-MOF-1.…”

Multifunctional AIEgen-based luminescent metal–organic frameworks with coordination-induced emission for chemical sensing

“…41 N-heterocycle pyrazine changes the p-bond structure; thus, TCPP sensitizes Eu 3+ ions for their antenna effect emission. Although there are some reports about TCPP, [43][44][45][46][47] the research is not comprehensive. The properties and applications of TCPP are still required to be explored.…”

Multi-functional metal–organic frameworks for detection and removal of water pollutions

“…7). 126 The In(tcpp) showed dual functions for sensing and removal of fluorinated chemicals. Specifically, In(tcpp) displayed a turn-on detection of F À within 5 min and showed a limit of detection of 1.3 mg L À1 .…”