A suggested mechanism for the visible chemiluminescence observed in gas phase aluminum oxidation

Kolb, C. E.; Gersh, Michael E.; Herschbach, D. R.

doi:10.1016/0010-2180(75)90066-8

Cited by 31 publications

(2 citation statements)

References 36 publications

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“…Reaction channels and their enthalpies of reaction that are thermodynamically accessible at our experimental temperatures Al(2P°1/2) + H20 -A10H2 AH^= -8 kcal mol"1 u•13'14 (2) Al(2P°1/2) + H20 -HAIOH AH^= -44 kcal mol-19,11-13 (3) Al(2P°1/2) + H20 -AlOH + H AHnn = -12 kcal mol"1 19 The enthalpy change of reaction 2 is an average from theoretical calculations. The enthalpy change of reaction 3 is obtained from theoretical calculations and matrix studies and could be uncertain by as much as ±15 kcal mol-1.12 Since the reaction rates were pressure independent, any adduct formation or insertion (cf.…”

Section: Resultsmentioning

confidence: 88%

Kinetics of the reaction aluminum(2P0) + water over an extended temperature range

McClean¹,

Nelson²,

Campbell³

1993

J. Phys. Chem.

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Section: Resultsmentioning

confidence: 88%

Kinetics of the reaction aluminum(2P0) + water over an extended temperature range

McClean¹,

Nelson²,

Campbell³

1993

J. Phys. Chem.

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“…They suggested that Al 2 could be formed by the initial oxidation of TMA and the source of the water could be outgassing of the rocket body. Kolb and Gersh provided evidence for AlO* as the emitting species and suggest Al 2 + O as a possible source of this excited species.…”

Section: Active Chemical Release Experimentsmentioning

confidence: 99%

Ambient and Modified Atmospheric Ion Chemistry: From Top to Bottom

2015

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CONTENTS 1. Introduction 4542 1.1. Historical Overview and Goals 4542 1.2. Background Basics of the Atmosphere 4543 2. The Exosphere 4545 3. Thermosphere 4546 3.1. Composition and Positive Ion Chemistry 4546 3.2. Ion−Molecule Reactions 4547 3.2.1. O 2 + Reactions 4547 3.2.2. O + Reactions 4548 3.2.3. N + Reactions 4550 3.2.4. N 2 + Reactions 4550 3.3. Airglow and Dissociative Recombination 4551 4. Mesosphere 4552 4.1. Positive Ion Composition and Chemistry 4552 4.2. Negative Ion Composition and Chemistry 4554 4.3. Mutual Neutralization 4555 4.4. Meteoric Smoke 4555 5. Stratosphere and Troposphere 4556 5.1. Acid−Base Chemistry 4556 5.2. Ion-Induced (Mediated) Nucleation 4558 6. Active Chemical Release Experiments 4559 6.1. Background and Historical Perspective 4559 6.2. Atmospheric Tracer Experiments 4559 6.3. Plasma Enhancement Releases − Samarium Chemi-ionization 4560 6.4. Plasma Depletion Experiments − Ionospheric Holes 4561 6.5. Plasma Depletion Experiments − Electron Holes 4562 7. Summary and Conclusions 4564 Author Information 4565 Corresponding Author 4565 Notes 4565 Biographies 4565 Acknowledgments 4566 References 4566

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Electronic Chemiluminescence in Gases

Menzinger¹

1980

Advances in Chemical Physics

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A suggested mechanism for the visible chemiluminescence observed in gas phase aluminum oxidation

Cited by 31 publications

References 36 publications

Kinetics of the reaction aluminum(2P0) + water over an extended temperature range

Kinetics of the reaction aluminum(2P0) + water over an extended temperature range

Ambient and Modified Atmospheric Ion Chemistry: From Top to Bottom

Electronic Chemiluminescence in Gases

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