Abstract:Every year, millions of tons of red mud (RDM) are created across the globe. Its storage is a major environmental issue due to its high basicity and tendency for leaching. This material is often kept in dams, necessitating previous attention to the disposal location, as well as monitoring and maintenance during its useful life. As a result, it is critical to develop an industrial solution capable of consuming large quantities of this substance. Many academics have worked for decades to create different cost-eff… Show more
“…In the meantime, the Rp of carbon steel B450C was ≈32 times lower in magnitude, and its initial value for the passive layer thickness of ≈0.1 nm tended to disappear. (7) The greater values of the passive layer thickness formed on SS430 and B450C steels during their exposure to the PC extract solution (previously reported) were ascribed to the more alkaline pH of that extract solution due to the higher content of Ca 2+ (in the absence of chloride ions), which was closely related to the greater Rp values of both steels compared to those obtained for the super sulfated (SS1) and sodium silicate modified limestone-Portland cement extract (JLSC1). (8) The reported results indicated that the change in time of pH and the free corrosion potential (OCP) values were decisively dependent on the cement composition and that of the ions' presence in the extract solution.…”
Section: Discussionmentioning
confidence: 99%
“…The two of the most common alternative types of cement include: (a) blended cement, in which PC is partially replaced by one or more supplementary cementitious materials (limestone, blast furnace slag, fly ash, calcinated clays, natural pozzolan, waste glass, etc.) [ 4 , 5 , 6 , 7 , 8 , 9 , 10 ]; and (b) alkali-activated cement (AAC), based on the reaction of a precursor (i.e., the supplementary cementitious materials referred above, limestone, etc.) and alkaline activators (alkali silicates and/or hydroxides) [ 11 ].…”
Stainless steel SS430 and carbon steel B450C were exposed for 30 days to the aqueous extract of sodium silicate-modified limestone-Portland cement as an alternative for the partial replacement of the Portland cement clinker. The initial pH of 12.60 was lowered and maintained at an average of 9.60, associated with air CO2 dissolution and acidification. As a result, the carbon steel lost its passive state, and the corrosion potential (OCP) reached a negative value of up to 296 mV, forming the corrosion layer of FeO, and FeOOH. In the meaning time, on the stainless steel SS430 surface, a passive layer of Cr2O3 grew in the presence of FeO, Fe2O3 and Cr(OH)3 corrosion products; thus, the OCP shifted to more positive values of +150 mV. It is suggested that a self-repassivation process took place on the SS430 surface due to the accumulation of alkaline sulfates on the interface. Because of the chloride attack, SS430 presented isolated pits, while on B450C, their area was extended. The quantitative analysis of EIS Nyquist and Bode diagrams revealed that the Rp of the corrosion process for SS430 was 2500 kΩcm2, ≈32 times lower in magnitude than on B450C, for which the passive layer tended to disappear, while that on SS430 was ≈0.82 nm.
“…In the meantime, the Rp of carbon steel B450C was ≈32 times lower in magnitude, and its initial value for the passive layer thickness of ≈0.1 nm tended to disappear. (7) The greater values of the passive layer thickness formed on SS430 and B450C steels during their exposure to the PC extract solution (previously reported) were ascribed to the more alkaline pH of that extract solution due to the higher content of Ca 2+ (in the absence of chloride ions), which was closely related to the greater Rp values of both steels compared to those obtained for the super sulfated (SS1) and sodium silicate modified limestone-Portland cement extract (JLSC1). (8) The reported results indicated that the change in time of pH and the free corrosion potential (OCP) values were decisively dependent on the cement composition and that of the ions' presence in the extract solution.…”
Section: Discussionmentioning
confidence: 99%
“…The two of the most common alternative types of cement include: (a) blended cement, in which PC is partially replaced by one or more supplementary cementitious materials (limestone, blast furnace slag, fly ash, calcinated clays, natural pozzolan, waste glass, etc.) [ 4 , 5 , 6 , 7 , 8 , 9 , 10 ]; and (b) alkali-activated cement (AAC), based on the reaction of a precursor (i.e., the supplementary cementitious materials referred above, limestone, etc.) and alkaline activators (alkali silicates and/or hydroxides) [ 11 ].…”
Stainless steel SS430 and carbon steel B450C were exposed for 30 days to the aqueous extract of sodium silicate-modified limestone-Portland cement as an alternative for the partial replacement of the Portland cement clinker. The initial pH of 12.60 was lowered and maintained at an average of 9.60, associated with air CO2 dissolution and acidification. As a result, the carbon steel lost its passive state, and the corrosion potential (OCP) reached a negative value of up to 296 mV, forming the corrosion layer of FeO, and FeOOH. In the meaning time, on the stainless steel SS430 surface, a passive layer of Cr2O3 grew in the presence of FeO, Fe2O3 and Cr(OH)3 corrosion products; thus, the OCP shifted to more positive values of +150 mV. It is suggested that a self-repassivation process took place on the SS430 surface due to the accumulation of alkaline sulfates on the interface. Because of the chloride attack, SS430 presented isolated pits, while on B450C, their area was extended. The quantitative analysis of EIS Nyquist and Bode diagrams revealed that the Rp of the corrosion process for SS430 was 2500 kΩcm2, ≈32 times lower in magnitude than on B450C, for which the passive layer tended to disappear, while that on SS430 was ≈0.82 nm.
“…The characteristic studies conclude that red mud reacting with water molecules releases OHions contributing to high pH. With suitable treatment methods, red mud can be converted into cementitious material and used in the construction industry [1]. As per the studies, red mud calcined…”
The manufacturing process of aluminum results in a toxic and highly alkaline by-product, red mud. The chemical composition of red mud varies based on the applied conditions during the production of aluminum. However, hematite (α-Fe 2 O 3 ), goethite (α-FeOOH), boehmite (γ-AlO(OH)), and quartz (SiO 2 ) are the major compounds and calcite (CaCO 3 ) and gibbsite (Al(OH) 3 ) are the minor compounds that constitute in the raw red mud. The characteristic studies conclude that red mud reacting with water molecules releases OHions contributing to high pH. With suitable treatment methods, red mud can be converted into cementitious material and used in the construction industry [1]. As per the studies, red mud calcined
“…Therefore, it is urgent to find alternative materials or materials that can partially replace fly ash. (Al-Hashem et al, 2022) proposed using metakaolin as a substitute material for cement and conducted research on its mechanics and durability, suggesting that metakaolin may be a potential substitute material for concrete (Qureshi et al, 2022).…”
The hydration reaction of mass concrete seriously endangers the structural safety. At present, the concrete production relies excessively on fly ash due to hydration reaction. In view of the problem that the demand of fly ash exceeds the supply, this paper proposes to use dacite powder to partially replace fly ash as the raw material for preparing cementitious materials. Through comprehensive tests and microstructure tests, various properties of dacite powder and fly ash composite cementitious materials are studied. The results show that: 1. The dacite powder with a specific surface area of 650 m2/kg, a fineness of 15% under laser particle size and a ball-milling time of 1.0 h has the best performance. 2. It is advisable to mix dacite powder and fly ash. The total amount of dacite powder should not exceed 30% of the cementitious material. It has the best performance when the amount of dacite powder and fly ash is the same. 3. The alkali activity of aggregate can hardly be inhibited by mixing dacite powder alone. The recommended measures to inhibit the alkali activity of aggregate are: i) mixing more than 20% fly ash alone. ii) mixed with 25% dacite powder and more than 15% fly ash.
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