Various
thermodynamic parameters of the binary mixtures of [diisopropylamine
(DIIPA) + 2-methyl-1-propanol, + 2-propanol, and + 1-butanol] have
been measured over the entire composition range and at a temperature
range of (293.15 to 313.15) K. Here, the Redlich–Kister type
polynomial equation is used to derive the coefficients and standard
deviations. The negative value obtained for excess molar volume (V
m
E
) and excess molar isentropic
compressibility (K
S,m
E
) shows the presence of strong molecular interactions. The calculated
apparent molar volume, V
φ,1, and
apparent molar compressibility, K
φ,1, predicts volume contraction of the solution with the addition of
alcohol in DIIPA. The obtained excess molar volume (V
m
E
) has then been correlated by using the Prigogine–Flory–Patterson
(PFP) theory.