A Study of the Structure and Physicochemical Properties of the Mixed Basicity Iron Ore Sinter
Andrey N. Dmitriev,
Elena A. Vyaznikova,
Galina Yu. Vitkina
et al.
Abstract:To study the influence of sinter basicity on the microstructure, phase composition, and physicochemical and metallurgical properties, samples of agglomerates with different basicities were sintered and investigated. A comprehensive study of the structure, composition, chemical, and metallurgical properties of the sinter was conducted, and the optimum values for these properties were determined. The results of the mineralogical transformations that occurred during the sintering process are also presented. The m… Show more
“…In addition, the rational B-spline method was used to smooth out noise that is present in the data. In contrast to machine learning methods or Bayesian classification models [53][54][55][56], deterministic models were used. The obtained response surfaces were visualized in "gnuplot" software [57,58], analogously with [59].…”
From a commercial viewpoint, mine methane is the most promising object in the field of reducing emissions of climate-active gases due to circular waste management. Therefore, the task of this research is to estimate the technogenic reservoirs resources of mine methane when implementing the circular waste management concept. The novelty of the authors’ approach lies in reconstructing the response space for the dynamics of methane release from the front and cross projections: CH4 = ƒ(S; t) and CH4 = ƒ(S; L), respectively. The research established a polynomial dependence of nonlinear changes in methane concentrations in the mixture extracted by type 4 wells when a massif is undermined as a result of mining in a full-retreat panel. And the distance from the face to the start of mining the panel is reduced by 220 m. For this reason, the emission of mine methane, in case of degasification network disruption in 15 days, can amount to more than 660 thousand m3 only for wells of type no. 4.
“…In addition, the rational B-spline method was used to smooth out noise that is present in the data. In contrast to machine learning methods or Bayesian classification models [53][54][55][56], deterministic models were used. The obtained response surfaces were visualized in "gnuplot" software [57,58], analogously with [59].…”
From a commercial viewpoint, mine methane is the most promising object in the field of reducing emissions of climate-active gases due to circular waste management. Therefore, the task of this research is to estimate the technogenic reservoirs resources of mine methane when implementing the circular waste management concept. The novelty of the authors’ approach lies in reconstructing the response space for the dynamics of methane release from the front and cross projections: CH4 = ƒ(S; t) and CH4 = ƒ(S; L), respectively. The research established a polynomial dependence of nonlinear changes in methane concentrations in the mixture extracted by type 4 wells when a massif is undermined as a result of mining in a full-retreat panel. And the distance from the face to the start of mining the panel is reduced by 220 m. For this reason, the emission of mine methane, in case of degasification network disruption in 15 days, can amount to more than 660 thousand m3 only for wells of type no. 4.
Iron ore sinter is one of most extensively utilised ferrous burdens for blast furnace (BF) worldwide. The sinter quality greatly depends on the microstructure and chemical compositions of calcium ferrites which is significantly affected by sinter basicity (mass ratio of CaO to SiO2). The characterisation of iron ore sinter products with varying binary basicity (CaO/SiO2) from 1.5 to 2.7 was studied by using optical microscopy and scanning electron microscopy-energy spectrometer (SEM-EDS). The results show that the change of sinter basicity changes the microstructure and composition of silico-ferrite of calcium and aluminium (SFCA), and more dendritic shape composite calcium ferrite (SFCA) with Fe-rich/low-Si is generated. Under the optical microscope, statistical results of the sinter reveal that with the increase in basicity, the aspect ratio of calcium ferrite increases from 2.35 to 7.69, indicating a gradual refinement of the crystals. Moreover, the distribution of crystals becomes more uniform, and the size of pores between crystals also decreases gradually, thereby the mechanical properties of the sinter from a microscopic structural perspective being enhanced. SEM-EDS analysis studies have found a certain linear relationship between the aspect ratio of SFCA and its iron content, where higher iron content in SFCA leads to finer and narrower SFCA formations. Additionally, an increase in basicity favours the generation of more composite calcium ferrite (SFCA) with Fe-rich/low-Si characteristics, which significantly improves the reducibility of the sinter. Moreover, what is even more interesting is that the iron content in SFCA shows an inverse relationship with the content of silicon, calcium and aluminium elements, yet it is directly proportional to the quaternary basicity [(CaO + MgO)/(SiO2 + Al2O3)] in SFCA.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.