2004
DOI: 10.1016/j.jcis.2004.05.014
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A study of the interaction between dialkyldimethylammonium bromides and tri-n-octylphosphine oxide (topo) in mixed monolayers at the air/water interface

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Cited by 7 publications
(5 citation statements)
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“…Beyond Xpeptide = 0.3, negative ΔGexc and ΔGmix values were observed, suggesting greater attractive interactions between the molecules in the mixed film in comparison to the ideal behaviour and higher thermodynamic stability than in unmixed films. Similar results showing simultaneous positive and negative deviations from the ideal behaviour were obtained by Hac-Wydro et al [45].…”
Section: Excess Propertiessupporting
confidence: 88%
“…Beyond Xpeptide = 0.3, negative ΔGexc and ΔGmix values were observed, suggesting greater attractive interactions between the molecules in the mixed film in comparison to the ideal behaviour and higher thermodynamic stability than in unmixed films. Similar results showing simultaneous positive and negative deviations from the ideal behaviour were obtained by Hac-Wydro et al [45].…”
Section: Excess Propertiessupporting
confidence: 88%
“…The analysis of Langmuir monolayers formed by dialkyldimethylammonium salts has already been presented in our former paper [26]. Based on the compression modulus values (defined as C −1 s = −A(dπ/dA) [27]), it was found that DTDAB and DHDAB form monolayers of a liquid type.…”
Section: Resultsmentioning
confidence: 99%
“…5 min in order to ensure complete evaporation of the solvent before compression was initiated. Since no influence of the compression velocity (within the range 25-75 cm 2 /min) was found for the investigated compounds [26], in all the experiments monolayers were compressed at 50 cm 2 /min. All experiments were repeated twice to ensure consistent results.…”
Section: Methodsmentioning
confidence: 99%
“…It is, therefore, interesting to relate the structure of surfactants to their properties, such as their ability to reduce surface tension or to form micelles. Extensive studies have been made to find a correlation between the structure of the cationic surfactants and their surface properties [13][14][15][16].…”
Section: Introductionmentioning
confidence: 99%