This work presents a quantitative test of SOLPS-ITER simulations against TCV L-mode experiments. These simulations account for drifts, currents, kinetic neutrals and carbon impurities providing the most complete edge transport simulations for TCV to date. The comparison is performed on nominally identical discharges carried out to assess the effectiveness of TCV's divertor baffles in the framework of the European PEX program (Plasma EXhaust) and employs numerous edge diagnostics providing a detailed code-experiment benchmark for TCV. The simulations show qualitative consistency, but quantitative differences remain that are assessed herein. It is found that, for a given separatrix density, the simulations most notably yield a colder, and denser, divertor state with higher divertor neutral pressure than measured.