We have studied the optical beam-foil spectra of Li, Be, and Mg in the wavelength region 200-550nm by use of a quantum efficiency calibrated monochromator at projectile energies of 210keV for Li, 156, 256, and 356keV for Be, and 100keV for Mg. The relative population for different Rydberg levels of the same term series decreases in most cases somewhat faster than (n*) -a, as is also observed in ion-atom encounters under single collision conditions. The relative level population for levels of the same principal quantum number increases generally with the orbital angular momentum quantum number, and superimposed on this increase is a peaking for p levels. The relative population of levels of the same charge state and with the same core configuration is unaffected by change of the projectile energy.