As a kind of traditional heating and power equipment, the industrial boiler is more and more applied in industrial production and life. However, due to the uneven heating of the boiler, the process of using the boiler would result in boiler leakage accidents and cause burns to workers. Given the above situation, the intelligent control system of the industrial boiler is studied in this paper to achieve safe and stable operation of the boiler. This design uses the distributed thermocouple temperature measurement method to design the boiler safety warning system based on the thermocouple sensor collaborative monitoring. Multiple sensors are used to cooperatively monitor and collect boiler operating signals. COMSOL model is used to realize 3D temperature field simulation and reconstruction inside the furnace lining, and the results are presented as early warning results through LabVIEW upper computer interface, which solves the shortcomings of low acquisition accuracy, narrow measurement accuracy, and single measurement method of the traditional contact measurement method. The practice shows that the system has the advantages of low cost, convenient installation and maintenance, easy expansion, high reliability, and strong anti-interference.