A study of active sites for partial oxidation on α-Bi2Mo3O12 and β-Bi2Mo2O9 catalysts using crystal structure visualization

Roles of bulk γ(L)-Bi2MoO6 and surface β-Bi2Mo2O9 in the selective catalytic oxidation of C3H6

“…[11] The crystal structure visualizations indicated that the α-phase consists of  1  1 and α 2 α 3 twin tetrahedral structures, and that the Mo ions are nearly in the same plane as the Bi ions, which demonstrated in ref. [11].…”

“…[11] The crystal structure visualizations indicated that the α-phase consists of  1  1 and α 2 α 3 twin tetrahedral structures, and that the Mo ions are nearly in the same plane as the Bi ions, which demonstrated in ref. [11]. By employing deuterated propene and microwave spectroscopy techniques, we previously reported and proposed that a rapid equilibration between the -allyl and the -allyl species occurs on the Mo ions of the α-phase [22].…”

“…The application Dispcrystal [11] was developed using the space group method. Lattice constants for the β-, γ(L)-and γ(H)-phases and the values of the x, y, and z coordinates for all atoms are provided in the attached CIF data, i.e., crystal structure data [10,14,15].…”

Photocatalytic removal of nitric oxide by Bi2Mo3O12 prepared by co-precipitation method

“…Previous studies have shown that the lay of Bi and Mo sites in the same plane seems to be important for redox features of Mo and Bi sites, i.e. some electrons can transfer between them during reactions [14].…”

Gas-phase dehydration of glycerol over commercial Pt/γ-Al2O3 catalysts

“…Acrolein is currently produced by gas-phase oxidation of propene with a Bi-Mo-V mixed oxide catalyst [11,12]. Production of acrolein from surplus glycerol by catalytic dehydration leads to oil saving and cost lowering [13].…”