AlN/GaN heterostructures are pursued for high-speed and high-power devices due to the superiority of their highmobility and high-density two-dimensional electron gas. However, the Ohmic contacts for high-mobility AlN/GaN heterostructures are difficult to realize, while the reason remains unrevealed. In this article, we reported a low-resistive Ohmic contact in AlN/GaN heterostructures with a high electron mobility of 1510 cm 2 V −1 s −1 by simply using rapid thermal annealing. Transmission electron microscopy analysis confirms that the incorporation of oxygen is the main impediment for Ohmic contacts, which forms Al 2 O 3 and voids in the interlayers and induces a near-open-circuit contact. By suppressing the incorporation of oxygen, a complete polycrystalline alloy without oxides is achieved, with a low contact resistance of ∼0.33 Ω•mm as an optimized result. Furthermore, the restrictions for Ohmic contacts in a high-mobility AlN/GaN heterostructure are also clarified, which are ascribed to the lack of an adequate Ti + AlN reaction. Giving a physical model of the contact formation as well as providing improved contact resistance via simplified techniques, this study is indicative of the enhanced functioning of versatile devices.