Piezoelectric
hydrogel sensors are becoming increasingly
popular
for wearable sensing applications due to their high sensitivity, self-powered
performance, and simple preparation process. However, conventional
piezoelectric hydrogels lack antifreezing properties and are thus
confronted with the liability of rupture in low temperatures owing
to the use of water as the dispersion medium. Herein, a kind of piezoelectric
organohydrogel that integrates piezoelectricity, low-temperature tolerance,
mechanical robustness, and stable electrical performance is reported
by using poly(vinylidene fluoride) (PVDF), acrylonitrile (AN), acrylamide
(AAm), p-styrenesulfonate (NaSS), glycerol, and zinc
chloride. In detail, the dipolar interaction of the PVDF chain with
the PAN chain facilitates the crystal phase transition of PVDF from
the α to β phase, which endows the organohydrogels with
a high piezoelectric constant d
33 of 35
pC/N. In addition, the organohydrogels are highly ductile and can
withstand significant tensile and compressive forces through the synergy
of the dipolar interaction and amide hydrogen bonding. Besides, by
incorporating glycerol and zinc chloride, the growth of ice crystals
is inhibited, allowing the organohydrogels to maintain stable flexibility
and sensitivity even at −20 °C. The real-time monitoring
of the pulse signal for up to 2 min indicates that the gel sensor
has stable sensitivity. It is believed that our organohydrogels will
have good prospects in future wearable electronics.