2023
DOI: 10.1039/d3ce00370a
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A stable 2D luminescent metal–organic framework as a highly sensitive sensor for Fe3+and Cr2O72−/CrO42−in water

Abstract: By reacting N,Nʹ-bis(3,5-dicarboxyphenyl)oxalamide (H4BDPO) with d10 electronic configuration Cd2+ ion under solvothermal conditions to produce a two-dimensional (2D) metal-organic framework (MOF), {[Cd3(HBDPO)2(H2O)7]·4H2O}n (1), which has been further characterized by different...

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Cited by 5 publications
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“…Similar phenomenon has been reported in other MOFs with uncoordinated carboxylate oxygen atoms. [30,31] Meanwhile, fluorescence lifetime of MOF-1 before and after sensing Fe 3 + and Cr 2 O 7 2À were also recorded. The reduced fluorescence lifetime in the present of Fe 3 + and Cr 2 O 7 2À confirmed dynamic quenching process (Figure S10).…”
Section: Luminescent Quenching Mechanismmentioning
confidence: 99%
“…Similar phenomenon has been reported in other MOFs with uncoordinated carboxylate oxygen atoms. [30,31] Meanwhile, fluorescence lifetime of MOF-1 before and after sensing Fe 3 + and Cr 2 O 7 2À were also recorded. The reduced fluorescence lifetime in the present of Fe 3 + and Cr 2 O 7 2À confirmed dynamic quenching process (Figure S10).…”
Section: Luminescent Quenching Mechanismmentioning
confidence: 99%