A square planar silylene nickel four-membered ring

Kaufmann, Sebastian; Köppe, Ralf; Roesky, Peter W.

doi:10.1039/d1dt02846d

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Dalton Trans.

2021

DOI: 10.1039/d1dt02846d

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A square planar silylene nickel four-membered ring

Sebastian Kaufmann

Ralf Köppe

Peter W. Roesky

Abstract: The square planar ring [PhC(NtBu)2SiNi(C5Me5)]2 was obtained by an insertion of a Ni(0) precusor in the Si–C bond of the silylene [PhC(NtBu)2Si(C5Me5)].

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2024

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Tuning the Inorganic Core of a reduced Ni₂Ge₂ Cluster

Theulier,

Bajo,

López‐Serrano

et al. 2024

Chemistry A European J

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Tetranuclear cores (M–E)2 of transition metals (M) and tetrylenes (EII = Si, Ge, Sn) are key motifs in homogeneous and heterogeneous catalysis. They exhibit a continuum of M–M and E–E bonding within the inorganic core that leads to a variety of structures for which there are no specific synthetic methods. Herein, we report a series of highly reduced [Ni0GeII]2 squares solely stabilized by bulky terphenyl (C6H3‐2,6‐Ar2) ligands, for which we provide complementary and high‐yielding syntheses. Reactivity studies with common Lewis bases (carbene and CO) evince that the structure of the (M–E)2 core can be finely tuned. We have investigated this core modification by computational means, offering a rationale to better understand the continuum of bonding across these clusters.

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Tuning the Inorganic Core of a reduced Ni₂Ge₂ Cluster

Theulier,

Bajo,

López‐Serrano

et al. 2024

Chemistry A European J

View full text Add to dashboard Cite

show abstract

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A square planar silylene nickel four-membered ring

Abstract: The square planar ring [PhC(NtBu)2SiNi(C5Me5)]2 was obtained by an insertion of a Ni(0) precusor in the Si–C bond of the silylene [PhC(NtBu)2Si(C5Me5)].

Cited by 1 publication

References 70 publications

Tuning the Inorganic Core of a reduced Ni₂Ge₂ Cluster

Tuning the Inorganic Core of a reduced Ni₂Ge₂ Cluster

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A square planar silylene nickel four-membered ring

Abstract: The square planar ring [PhC(NtBu)2SiNi(C5Me5)]2 was obtained by an insertion of a Ni(0) precusor in the Si–C bond of the silylene [PhC(NtBu)2Si(C5Me5)].

Cited by 1 publication

References 70 publications

Tuning the Inorganic Core of a reduced Ni2Ge2 Cluster

Tuning the Inorganic Core of a reduced Ni2Ge2 Cluster

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Tuning the Inorganic Core of a reduced Ni₂Ge₂ Cluster

Tuning the Inorganic Core of a reduced Ni₂Ge₂ Cluster