2015
DOI: 10.1016/j.ssi.2014.11.015
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A sodium ion conducting gel polymer electrolyte

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Cited by 157 publications
(126 citation statements)
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“…287 On the other hand, the use of gel polymer electrolytes (GPEs) to replace flammable organic electrolytes has also been proposed to address the safety concerns and avoid liquid leakage for SIBs. [288][289][290] The first report indicated that a Na + ion conducting GPE based on poly(vinylidene difluoride-co-hexafluoropropylene) (PVDF-HFP) was prepared by a simple phase separation process, and showed an acceptable ionic conductivity of 0.60 mS cm ─1 , good mechanical properties and good electrochemical stability. 288 Then, a Na-ion capacitor assembled with this GPEs provided high specific energy of 168 Wh kg ─1 and stable cycling with 85 % of the specific capacitance maintained after 1200 cycles.…”
Section: Sodium-ion Batteriesmentioning
confidence: 99%
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“…287 On the other hand, the use of gel polymer electrolytes (GPEs) to replace flammable organic electrolytes has also been proposed to address the safety concerns and avoid liquid leakage for SIBs. [288][289][290] The first report indicated that a Na + ion conducting GPE based on poly(vinylidene difluoride-co-hexafluoropropylene) (PVDF-HFP) was prepared by a simple phase separation process, and showed an acceptable ionic conductivity of 0.60 mS cm ─1 , good mechanical properties and good electrochemical stability. 288 Then, a Na-ion capacitor assembled with this GPEs provided high specific energy of 168 Wh kg ─1 and stable cycling with 85 % of the specific capacitance maintained after 1200 cycles.…”
Section: Sodium-ion Batteriesmentioning
confidence: 99%
“…[288][289][290] The first report indicated that a Na + ion conducting GPE based on poly(vinylidene difluoride-co-hexafluoropropylene) (PVDF-HFP) was prepared by a simple phase separation process, and showed an acceptable ionic conductivity of 0.60 mS cm ─1 , good mechanical properties and good electrochemical stability. 288 Then, a Na-ion capacitor assembled with this GPEs provided high specific energy of 168 Wh kg ─1 and stable cycling with 85 % of the specific capacitance maintained after 1200 cycles. 234 Also, a Na-ion battery Sb/Na3V2(PO4)3 with a low-cost GPE based on cross-linked PMMA was demonstrated.…”
Section: Sodium-ion Batteriesmentioning
confidence: 99%
“…The value of ionic transference number, t i can be estimated from the normalized current versus time plot using the equation; (2) where i e and i T are the electronic and total current respectively. The cationic (sodium) transference number (t Na + ) of the GPE film was evaluated using the combination of DC polarization and AC impedance technique [8].…”
Section: Transference Numbermentioning
confidence: 99%
“…Sodium-ion (Na-ion) battery represents a possible alternative, which stands out because sodium is cheaper, non-toxic, high electrochemical potential and more abundant than lithium. Due to this, the studies of sodium ion conducting electrolytes recently have drawn attention of many researchers worldwide [1][2][3].…”
Section: Introductionmentioning
confidence: 99%
“…Up till now, there are several reports on solid-state Na ion batteries. [13][14][15] However, no studies are available on solid-state Na ion capacitor to the best of our knowledge.Herein, on the basis of our continuous studies on gel polymer electrolyte (GPE) systems for Li + and Na + ion batteries, [16][17][18][19][20][21][22] we are successful in constructing the fi rst quasisolid-state NIC with an Na + ion conducting gel polymer electrolyte (N-GPE), which can achieve an energy density of over 160 W h kg −1 based on the total mass of positive and negative electrode materials. Furthermore, it shows stable cycling with 85% retention of the specifi c capacitance after 1200 cycles.…”
mentioning
confidence: 99%