2009
DOI: 10.1243/09544070jauto1095
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A simplified model for natural-gas vehicle catalysts with honeycomb and foam substrates

Abstract: A mathematical model is developed for the simulation of the chemical and transport phenomena in three-way catalysts for natural-gas vehicles, with honeycomb and foam substrates. The chemical phenomena are modelled on the basis of a simplified approach, which assumes that pollutant conversion is governed by oxygen storage and release dynamics. The transport phenomena, i.e. heat transfer, gas-phase mass transfer, washcoat diffusion, and pressure drop, are modelled on the basis of correlations adapted from the li… Show more

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Cited by 17 publications
(9 citation statements)
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“…In a previous study [14] we have demonstrated, using numerical simulation, that the foams are characterized by much higher mass transfer ratios from the bulk flow to the catalyst surface in respect to honeycombs. We have though pointed out that this advantage may be partly but also even completely offset by the lower available surface area for the chemical reactions.…”
Section: Figure 11 Co Oxidation Efficiency (Honeycomb Vs Foam) Figumentioning
confidence: 96%
See 1 more Smart Citation
“…In a previous study [14] we have demonstrated, using numerical simulation, that the foams are characterized by much higher mass transfer ratios from the bulk flow to the catalyst surface in respect to honeycombs. We have though pointed out that this advantage may be partly but also even completely offset by the lower available surface area for the chemical reactions.…”
Section: Figure 11 Co Oxidation Efficiency (Honeycomb Vs Foam) Figumentioning
confidence: 96%
“…Following a systematic development process, our laboratory has extensively investigated material issues, [11], the fluid dynamic behavior, [12,13], reactivity in the exhaust gas of natural gas engines [4,5], while using simulation for analyzing the underlying phenomena, [14]. In this study the focus was the realization of a foam based DOC for a small heavy duty truck.…”
Section: Introductionmentioning
confidence: 99%
“…Tsinoglou et al [17] has developed a mathematical model to study and compare the transport phenomenon between wash-coated honeycomb and ceramic foam substrates. They reported that a faster mass transfer rate in the gas phase and a slower diffusion rate through the pores of the wash coat (compared to the rates achieved using honeycomb substrates) could be achieved using ceramic foam.…”
Section: Literature Reviewmentioning
confidence: 99%
“…Chemical reactions have also been modelled based on simplified Arrhenius and Langmuir-Hinshelwood approaches. The associated parameters have been chosen by tuning experimental data starting from literature data taken from [10,11,12]. Up to now, CO oxidation has been taken into account under oxygen abundance, i.e., typical Diesel Oxidation Catalyst conditions.…”
Section: Simulation Modelmentioning
confidence: 99%