A simple route to synthesize new binary cobalt iron cyclotetraphosphate CoFeP4O12 using aqueous and acetone media

Boonchom, Banjong; Thongkam, Montree; Kongtaweelert, Samart; Vittayakorn, Naratip

doi:10.1016/j.jallcom.2009.07.036

Cited by 6 publications

(2 citation statements)

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“…One strategy is based on acidification of MCl 2 (M = Co, Fe, Mn, Ni, Cu) by [H 2 PO 4 ] − , followed by thermal treatment at high temperatures (≥600°C), leading to binary oligomeric systems of the general formula M 2 P 4 O 12 . [2][3][4][10][11][12][13][14][15][16][17][18][19] A second strategy developed by Kamimura et al comprises stirring a solution containing a salt of the cyclo-tetrametaphosphate ligand with the desired noble transition metal (such as rhodium, iridium, ruthenium, and palladium) at room temperature overnight. The desired product can then be obtained by further extraction and crystallization from dichloromethane and diethyl ether.…”

Section: Introductionmentioning

confidence: 99%

Facile synthesis of mononuclear early transition-metal complexes of κ³cyclo-tetrametaphosphate ([P₄O₁₂]⁴⁻) and cyclo-trimetaphosphate ([P₃O₉]³⁻)

et al. 2014

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We herein report the preparation of several mononuclear-metaphosphate complexes using simple techniques and mild conditions with yields ranging from 56% to 78%. Treatment of cyclo-tetrametaphosphate ([TBA]4[P4O12]·5H2O, TBA = tetra-n-butylammonium) with various metal sources including (CH3CN)3Mo(CO)3, (CH3CN)2Mo(CO)2(η(3)-C3H5)Cl, MoO2Cl2(OSMe2)2, and VOF3, leads to the clean and rapid formation of [TBA]4[(P4O12)Mo(CO)3]·2H2O, [TBA]3[(P4O12)Mo(CO)2(η(3)-C3H5)], [TBA]3[(P4O12)MoO2Cl] and [TBA]3[(P4O12)VOF2]·Et2O salts in isolated yields of 69, 56, 68, and 56% respectively. NMR spectroscopy, NMR simulations and single crystal X-ray studies reveal that the [P4O12](4-) anion behaves as a tridentate ligand wherein one of the metaphosphate groups is not directly bound to the metal. cyclo-Trimetaphosphate-metal complexes were prepared using a similar procedure i.e., treatment of [PPN]3[P3O9]·H2O (PPN = bis(triphenylphosphine)iminium) with the metal sources (CH3CN)2Mo(CO)2(η(3)-C3H5)Cl, MoO2Cl2(OSMe2)2, MoOCl3, VOF3, WOCl4, and WO2Cl2(CH3CN)2 to produce the corresponding salts, [PPN]2[(P3O9)Mo(CO)2(η(3)-C3H5)], [PPN]2[(P3O9)MoO2Cl], [PPN]2[(P3O9)MoOCl2], [PPN]2[(P3O9)VOF2]·2CH2Cl2, and [PPN]2[(P3O9)WO2Cl] in isolated yields of 78, 56, 75, 59, and 77% respectively. NMR spectroscopy, NMR simulations and single-crystal X-ray studies indicate that the trianionic ligand [P3O9](3-) in these complexes also has κ(3) connectivity.

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Section: Introductionmentioning

confidence: 99%

Facile synthesis of mononuclear early transition-metal complexes of κ³cyclo-tetrametaphosphate ([P₄O₁₂]⁴⁻) and cyclo-trimetaphosphate ([P₃O₉]³⁻)

et al. 2014

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“…Several classes of divalent/trivalent metals (Mn, Mg, Co, Cu, Fe, Cd, and Ni) are currently available to form monometallic tetrametaphosphate . Binary metal tetrametaphosphate M 2– x A x P 4 O 12 (M and A stand for Mg, Ca, Mn, Co, Ni, Zn, or Cu; x < 2), identical in structure to the M 2 P 4 O 12 , have been successfully fabricated by Trojan and Boonchom and Vittayakorn. All these compounds with monoclinic space group C 2/ c ( Z = 4) share similar X-ray diffraction patterns and approximate single-cell parameters .…”

Section: Introductionmentioning

confidence: 99%

Phytic Acid Assisted Fabrication of High Specific Surface Area Carbon-Wrapped Ni₂P₄O₁₂ Nanoparticle Electrodes for Lithium-Ion Battery

Pang,

Mao,

Liu

et al. 2024

ACS Sustainable Chem. Eng.

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Transition metal tetrametaphosphates (M2P4O12) are a novel electrode material for lithium-ion batteries (LIBs) due to their good electrical conductivity and reversible redox behavior. In this work, carbon layer self-encapsulated Ni2P4O12 nanoparticles were prepared by facile oil bath evaporation and high temperature calcination. A detailed investigation of the synthesis mechanism was performed through controlled variables. Among the various synthesis factors, the glucose introduction generates a self-coated carbon layer; the calcination temperature can directly affect the crystalline phase formation; the product was calcined at 800° equipped with the optimal lithium storage performance; the selection of organic phytic acid was correlated with the Ni2P4O12 micromorphology; and the dosage of phytic acid, while having an insignificant effect on the crystalline phase, strongly associated with lithium-ion storage. 4 mL of the phytic acid-synthesized Ni2P4O12 material showed the best lithium storage performance. On this basis, the fabricated NPO-PA-GL electrode materials were applied in LIBs, and electrochemical tests were conducted. Benefiting from the modulated electronic structure of the carbon layer, high specific surface area, and nanoparticle structure, the NPO-PA-GL electrode exhibited high-efficiency electrochemical activity. Particularly, the cell capacity amounted to 871.8 mA h g–1 at a current density of 50 mA g–1. After 500 constant-current charge/discharge cycles at 1 A g–1, the capacity increased by 128.4%. This work not only indicated that NPO-PA-GL would be a prospective LIB anode material but also pointed out a new direction for the exploitation of LIB anode materials, which will lead to significant innovations in sustainable chemistry and engineering.

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ChemInform Abstract: A Simple Route to Synthesize New Binary Cobalt Iron Cyclotetraphosphate CoFeP₄O₁₂ Using Aqueous and Acetone Media.

et al. 2010

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. -The new title compound is prepared by a simple, rapid, cost-effective, and environmental friendly route from a mixture of CoCO3, Fe, and H3PO4 in a water/acetone mixture (25°C, 10 min; annealing of the precipitate at 500°C for 3 h). CoFeP4O12 crystallizes in the monoclinic space group C2/c (powder XRD) and exhibits superparamagnetic behavior. The material may be useful for potential applications as super-phosphate and micronutrient fertilizer, inorganic ceramic pigment, and for corrosion-proof compositions.

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A simple route to synthesize new binary cobalt iron cyclotetraphosphate CoFeP4O12 using aqueous and acetone media

Cited by 6 publications

References 13 publications

Facile synthesis of mononuclear early transition-metal complexes of κ³cyclo-tetrametaphosphate ([P₄O₁₂]⁴⁻) and cyclo-trimetaphosphate ([P₃O₉]³⁻)

Facile synthesis of mononuclear early transition-metal complexes of κ³cyclo-tetrametaphosphate ([P₄O₁₂]⁴⁻) and cyclo-trimetaphosphate ([P₃O₉]³⁻)

Phytic Acid Assisted Fabrication of High Specific Surface Area Carbon-Wrapped Ni₂P₄O₁₂ Nanoparticle Electrodes for Lithium-Ion Battery

ChemInform Abstract: A Simple Route to Synthesize New Binary Cobalt Iron Cyclotetraphosphate CoFeP₄O₁₂ Using Aqueous and Acetone Media.

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A simple route to synthesize new binary cobalt iron cyclotetraphosphate CoFeP4O12 using aqueous and acetone media

Cited by 6 publications

References 13 publications

Facile synthesis of mononuclear early transition-metal complexes of κ3cyclo-tetrametaphosphate ([P4O12]4−) and cyclo-trimetaphosphate ([P3O9]3−)

Facile synthesis of mononuclear early transition-metal complexes of κ3cyclo-tetrametaphosphate ([P4O12]4−) and cyclo-trimetaphosphate ([P3O9]3−)

Phytic Acid Assisted Fabrication of High Specific Surface Area Carbon-Wrapped Ni2P4O12 Nanoparticle Electrodes for Lithium-Ion Battery

ChemInform Abstract: A Simple Route to Synthesize New Binary Cobalt Iron Cyclotetraphosphate CoFeP4O12 Using Aqueous and Acetone Media.

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Facile synthesis of mononuclear early transition-metal complexes of κ³cyclo-tetrametaphosphate ([P₄O₁₂]⁴⁻) and cyclo-trimetaphosphate ([P₃O₉]³⁻)

Facile synthesis of mononuclear early transition-metal complexes of κ³cyclo-tetrametaphosphate ([P₄O₁₂]⁴⁻) and cyclo-trimetaphosphate ([P₃O₉]³⁻)

Phytic Acid Assisted Fabrication of High Specific Surface Area Carbon-Wrapped Ni₂P₄O₁₂ Nanoparticle Electrodes for Lithium-Ion Battery

ChemInform Abstract: A Simple Route to Synthesize New Binary Cobalt Iron Cyclotetraphosphate CoFeP₄O₁₂ Using Aqueous and Acetone Media.