A Simple Methodology in Preparing NH4V3O8

Chen, Yanmei; Zhao, Xin-Fu; Ju, Zhenghua; Yao, Kaling; Hu, Zheng

doi:10.1080/15533170600728963

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2014

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Cited by 1 publication

(2 citation statements)

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“…In comparison with the literature [7], it can be seen that the crystal data and the structure of the title compound determined were almost consistent with the reported results (Table 1…”

Section: Structural Descriptionsupporting

confidence: 90%

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Low-Temperature Heat Capacities and Thermodynamic Properties of a New Complex [Na(H2O)2]6[MoCo6O12(H2O)12]•4.3H2O(s)

Meng

Xia

2014

AMM

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A new complex [Na (H2O)2]6[MoCo6O12(H2O)12]·4.3H2O(s) was synthesized and determined by X-ray crystallography. Low-temperature heat capacities of the compound was measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 380 K. An obvious dehydration process was found in the heat capacity curve of the title compound. The temperature, enthalpy and entropy of the dehydration process were determined to be (370.266±0.292) K, (187.455±0.354) kJ·mol-1, (50.627±0.078) J·K-1·mol-1 by three series of repeated heat capacity measurements in the region of thermal decomposition.

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“…In comparison with the literature [7], it can be seen that the crystal data and the structure of the title compound determined were almost consistent with the reported results (Table 1…”

Section: Structural Descriptionsupporting

confidence: 90%

“…Here we study the low-temperature heat capacities of a Anderson-type compound. The structure of the title compound have been reported by Yao [7], we mainly study the low-temperature heat capacities properties.…”

Section: Introductionmentioning

confidence: 99%

Low-Temperature Heat Capacities and Thermodynamic Properties of a New Complex [Na(H2O)2]6[MoCo6O12(H2O)12]•4.3H2O(s)

Meng

Xia

2014

AMM

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A Simple Methodology in Preparing NH₄V₃O₈

Cited by 1 publication

References 6 publications

Low-Temperature Heat Capacities and Thermodynamic Properties of a New Complex [Na(H<sub>2</sub>O)<sub>2</sub>]<sub>6</sub>[MoCo<sub>6</sub>O<sub>12</sub>(H<sub>2</sub>O)<sub>12</sub>]•4.3H<sub>2</sub>O(s)

Low-Temperature Heat Capacities and Thermodynamic Properties of a New Complex [Na(H<sub>2</sub>O)<sub>2</sub>]<sub>6</sub>[MoCo<sub>6</sub>O<sub>12</sub>(H<sub>2</sub>O)<sub>12</sub>]•4.3H<sub>2</sub>O(s)

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