A simple but highly sensitive and selective calixarene-based voltammetric sensor for serotonin

Wang, Fei; Wu, Yanju; Lü, Kui; Ye, Baoxian

doi:10.1016/j.electacta.2012.09.033

Cited by 64 publications

(31 citation statements)

References 35 publications

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“…P(EDOP)-SWNTs/GCE DPV 1.0 3 10 À7 -1.0 3 10 À5 5.0 3 10 À9 -[6] MIP-hemin Amperometry 1.0 3 10 À6 -1.0 3 10 À6 1.0 3 10 À3 Serum samples [22] CURC/GCE SWV 1.0 3 10 À7 -1.0 3 10 À5 3.0 3 10 À8 Human blood serum [38] Pt/MWCNT/PPy/AgNPs DPV 5.0 3 10 À7 -5.0 3 10 À6 1.5 3 10 À7 Plasmatic serum sample [16] MWCNT-Chitosan DPV 5.0 3 10 À8 -1.6 3 10 À5 5.0 3 10 À8 Serum samples [39] p(P3CA)/PGE AdDPSV 1.0 3 10 À8 -1.0 3 10 À6 2.5 3 10 À9 Blood serum Urine serum [19] Ion-selective electrode Potentiometry 2. …”

Section: Electrodesmentioning

confidence: 99%

“…P(EDOP)-SWNTs/GCE DPV 1.0 3 10 À7 -1.0 3 10 À5 5.0 3 10 À9 -[6] MIP-hemin Amperometry 1.0 3 10 À6 -1.0 3 10 À6 1.0 3 10 À3 Serum samples [22] CURC/GCE SWV 1.0 3 10 À7 -1.0 3 10 À5 3.0 3 10 À8 Human blood serum [38] Pt/MWCNT/PPy/AgNPs DPV 5.0 3 10 À7 -5.0 3 10 À6 1.5 3 10 À7 Plasmatic serum sample [16] MWCNT-Chitosan DPV 5.0 3 10 À8 -1.6 3 10 À5 5.0 3 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58…”

Section: Electrodesmentioning

confidence: 99%

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Electrochemical Determination of Serotonin Using Pre‐treated Multi‐walled Carbon Nanotube‐polyaniline Composite Electrode

2018

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In this study, the multiwalled carbon nanotube‐poly (aniline) (MWCNT‐PANI) composite is successfully deposited on the glassy carbon electrode (GCE) by electropolymerization as an efficient and conventional route. The structural and chemical properties of the MWCNT‐PANI was investigated by various spectroscopic and analytical techniques, scanning electron microscopy (SEM), X‐Ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). After that, the electrochemical oxidation behavior of serotonin (5‐HT) in phosphate buffer solution (pH 7.4) was examined using cyclic voltammetry (CV). Besides, the MWCNT‐PANI/GCE used for the detection of 5‐HT with linear concentration range (1.0×10−7–1.2×10−5 mol L−1), low limit of detection (3.3×10−8 mol L−1) under differential pulse voltammetric (DPV) conditions. The proposed electrochemical sensor based on MWCNT‐PANI is both time and cost effective, has good reproducibility, high selectivity as well as stability for 5‐HT determination. The developed composite electrode was used to detect 5‐HT in synthetic urine sample and satisfactory results were obtained with high recoveries.

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Section: Electrodesmentioning

confidence: 99%

“…P(EDOP)-SWNTs/GCE DPV 1.0 3 10 À7 -1.0 3 10 À5 5.0 3 10 À9 -[6] MIP-hemin Amperometry 1.0 3 10 À6 -1.0 3 10 À6 1.0 3 10 À3 Serum samples [22] CURC/GCE SWV 1.0 3 10 À7 -1.0 3 10 À5 3.0 3 10 À8 Human blood serum [38] Pt/MWCNT/PPy/AgNPs DPV 5.0 3 10 À7 -5.0 3 10 À6 1.5 3 10 À7 Plasmatic serum sample [16] MWCNT-Chitosan DPV 5.0 3 10 À8 -1.6 3 10 À5 5.0 3 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58…”

Section: Electrodesmentioning

confidence: 99%

Electrochemical Determination of Serotonin Using Pre‐treated Multi‐walled Carbon Nanotube‐polyaniline Composite Electrode

2018

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“…At first, most investigations related to calixarenes and their derivatives focused on their applications for metal ions [12][13][14][15][16][17]. At present, their applications for the determination of small biomolecules such as folic acid (FA) [18], DA [19], norepinephrine [20] and serotonin [21] ea al, is also raised. These sensors exhibited highly selective, but the sensitivity is not very satisfactory because of the nonconductivity of calixarenes.…”

Section: Introductionmentioning

confidence: 99%

Simultaneous voltammetric determination of dopamine and uric acid based on Langmuir–Blodgett film of calixarene modified glassy carbon electrode

Wang

Chang-long

et al. 2015

Sensors and Actuators B: Chemical

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“…In recent years, chemists often explore the host-guest binding interaction of water-soluble calixarenes and amino acids in several aspects. The properties of amino acids have been studied by various methods such as spectrofluorometry, 19 1 H NMR spectroscopy, 20 microcalorimetry, 21 reverse-phase high-performance liquid chromatography, 22 voltammetry 23 and other electrochemical methods. [24][25][26][27] Tryptophan, as one of most basic amino acids, plays an important role in the growth, development, and metabolism of humans and animals and has been attracting much attention in medicine.…”

Section: Introductionmentioning

confidence: 99%

Supramolecular p-sulfonated calix[4,6,8]arene for tryptophan detection

et al. 2014

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Numerous techniques have focused on the ability of p-sulfonated calix[n]arene to form complexes with tryptophan. Scanning electron microscopy and Fourier transform infrared spectroscopy were utilized to study the organization and molecular structure of different layers of the electrode surface. Scanning electron microscopy results showed that SC4A displayed a cubic structure whereas SC6A and SC8A displayed dendrite structures. The electrochemical properties and potential complex formation between SCnA and tryptophan were characterized by cyclic voltammetry and electrochemical impedance spectroscopy. Cyclic voltammetry experiments showed that the gold electrode was successfully functionalized by self-assembled cysteamine and SC4A. Electrochemical impedance spectroscopy results showed the observation of the tryptophan-SCnA interaction and indicated that SC4A had the highest sensitivity to tryptophan and allowed 2.04 g L −1 tryptophan to be detected. Electrochemical impedance spectroscopy analysis and molecular modeling calculation confirmed that SC4A has higher tryptophan sensitivity than SC6A and SC8A.Résumé : De nombreuses techniques ont été axées sur la capacité des calix[n]arènes p-sulfonés à former des complexes avec le tryptophane. La microscopie électronique à balayage et la spectroscopie infrarouge à transformée de Fourier ont été utilisées pour étudier l'organisation et la structure moléculaire de différentes couches de la surface de l'électrode. Les résultats de la microscopie électronique à balayage ont montré que SC4A présentait une structure cubique alors que SC6A et SC8A possédaient des structures dendritiques. Les propriétés électrochimiques et la formation possible d'un complexe entre SCnA et le tryptophane ont été caracté-risées par voltammétrie cyclique et spectroscopie d'impédance électrochimique. Les expériences de voltammétrie cyclique ont montré que l'électrode en or était fonctionnalisée avec succès par autoassemblage de cystéamine et de SC4A. Les résultats de la spectroscopie d'impédance électrochimique ont permis d'observer l'interaction tryptophane-SCnA et ont révélé que SC4A avait une sensibilité élevée au tryptophane et qu'une concentration en tryptophane de 2,04 g L −1 pouvait être détectée de cette technique d'analyse. Les calculs de modélisation moléculaire et les résultats de la spectroscopie d'impédance électrochimique ont confirmé que SC4A présentait une plus grande sensibilité au tryptophane que SC6A et SC8A. [Traduit par la Rédaction] Mots-clés : spectroscopie infrarouge à transformée de Fourier, calculs de modélisation moléculaire, voltammétrie cyclique, spectroscopie d'impédance électrochimique, microscopie électronique à balayage.

show abstract

A simple but highly sensitive and selective calixarene-based voltammetric sensor for serotonin

Cited by 64 publications

References 35 publications

Electrochemical Determination of Serotonin Using Pre‐treated Multi‐walled Carbon Nanotube‐polyaniline Composite Electrode

Electrochemical Determination of Serotonin Using Pre‐treated Multi‐walled Carbon Nanotube‐polyaniline Composite Electrode

Simultaneous voltammetric determination of dopamine and uric acid based on Langmuir–Blodgett film of calixarene modified glassy carbon electrode

Supramolecular p-sulfonated calix[4,6,8]arene for tryptophan detection

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