1976
DOI: 10.1039/c39760000317
|View full text |Cite
|
Sign up to set email alerts
|

A silatrane–platinum complex, trans-[PtCl{Si(OCH2CH2)3N}(PMe2Ph)2] with a planar nitrogen and No Si–N bond; X-ray crystal structure

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1
1
1

Citation Types

0
15
0
1

Year Published

1986
1986
2017
2017

Publication Types

Select...
5
3
1

Relationship

0
9

Authors

Journals

citations
Cited by 26 publications
(16 citation statements)
references
References 0 publications
0
15
0
1
Order By: Relevance
“…The tin atom displays a very distorted trigonal bipyramidal arrangement, with the osmium and nitrogen atoms axial, and the oxygen atoms equatorial. 7 The bonds about the nitrogen atom are almost perfectly trigonal planar with the sum of angles at N being 358.9°. The nitrogen atom is displaced 0.088(7) Å from the plane defined by C(6), C(8) and C(10) in the direction away from the metal atom.…”
mentioning
confidence: 98%
See 1 more Smart Citation
“…The tin atom displays a very distorted trigonal bipyramidal arrangement, with the osmium and nitrogen atoms axial, and the oxygen atoms equatorial. 7 The bonds about the nitrogen atom are almost perfectly trigonal planar with the sum of angles at N being 358.9°. The nitrogen atom is displaced 0.088(7) Å from the plane defined by C(6), C(8) and C(10) in the direction away from the metal atom.…”
mentioning
confidence: 98%
“…[2][3][4][5] Although many structurally characterised examples of silatranes have been reported, 6 only two bear metal atoms as axial substituents, and both of these feature strikingly long Si-N distances. 7,8 In contrast to silatranes, reports of the analogous tin compounds, stannatranes, are sparse, with only two crystallographically characterised examples. 9,10 Our recent work has focused on the synthesis of trihalostannyl osmium complexes because these complexes are amenable to further derivatisation at the tin centre.…”
mentioning
confidence: 99%
“…Phosphorylaminopropylsilatranes (134)(135)(136)(137)(138)(139)(140)(141)(142)(143)(144)(145) were systematically generated by nucleophillic substitution reaction of 2-chloro-1,3,2-dioxaphosphinanes and aminopropylsilatrane (Scheme 9) 88 The reaction was carried out in dichloromethane in the presence of triethylamine. The contents were added at 10 1C in about 1 h followed by constant stirring for 2-4 h at room temperature.…”
Section: Route 3: Reaction Of Silatrane With Suitable Reagent To Form...mentioning
confidence: 99%
“…There are five derivatives with the PtP 2 ClSi inner coordination sphere, four trans [432][433][434]436] and one cis [435]. In three of them [432][433][434] only unidentate ligands are involved.…”
Section: Pts 2 Xy and Ptp 2 Xymentioning
confidence: 99%