2009
DOI: 10.1002/ejic.200900123
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A Series of CuI Complexes Containing 1,10‐Phenanthroline Derivative Ligands: Synthesis, Characterization, Photophysical, and Oxygen‐Sensing Properties

Abstract: Five novel copper(I) complexes with the general formula [Cu(dpephos)(NN)]BF 4 {dpephos = bis [2-(diphenylphosphanyl) ,10]phenanthroline (aeip, 5)} were rationally designed and synthesized, and these complexes were characterized by 1 H NMR and IR spectroscopy and elemental analysis. X-ray crystalstructure analysis of 3 and 4 are also presented. Their photophysical properties at room temperature were examined by

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Cited by 53 publications
(27 citation statements)
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“…This linear SternVolmer curve can indeed simplify sensing operations since no calibration procedures are needed. Compared to similar sensing composites whose dopant are physically loaded, our SternVolmer curve is indeed improved by showing a better linearity [20,21]. Covalent grafting makes probe molecules uniformly distributed in supporting host, favoring linearity improvement.…”
Section: Sensing Mechanism and Stern-volmer Equationmentioning
confidence: 73%
“…This linear SternVolmer curve can indeed simplify sensing operations since no calibration procedures are needed. Compared to similar sensing composites whose dopant are physically loaded, our SternVolmer curve is indeed improved by showing a better linearity [20,21]. Covalent grafting makes probe molecules uniformly distributed in supporting host, favoring linearity improvement.…”
Section: Sensing Mechanism and Stern-volmer Equationmentioning
confidence: 73%
“…This may be due to the high electronic affinity of the oxadiazole moiety, which makes the phenyl group to be an electrondonating group. So the similar HOMO and LUMO energy levels of [Cu(bop)(PPh 3 …”
Section: Dft Calculationsmentioning
confidence: 78%
“…These data are consistent with the optical energy gaps, and the band gap trend is in good agreement with both the optical and electrochemical data. Due to the introduction of the CF 3 …”
Section: ) 2 ][Bf 4 ] and [Cu(pop)(pph 3 ) 2 ][Bf 4 ] Can Be Rationalmentioning
confidence: 99%
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“…6. What's more, it can be expected that [Cu(P-P) (N-N)] þ complexes with a large coplanar conjugation diamine ligand may offer higher sensitivities, while, a small coplanar conjugation diamine ligand may compromise the sensitivity performance [17,23].…”
Section: Further Analysis On Oxygen Sensing Mechanism Of [Cu(pop) (Ecmentioning
confidence: 97%