Abstract:Five novel copper(I) complexes with the general formula [Cu(dpephos)(NN)]BF 4 {dpephos = bis [2-(diphenylphosphanyl) ,10]phenanthroline (aeip, 5)} were rationally designed and synthesized, and these complexes were characterized by 1 H NMR and IR spectroscopy and elemental analysis. X-ray crystalstructure analysis of 3 and 4 are also presented. Their photophysical properties at room temperature were examined by
“…This linear SternVolmer curve can indeed simplify sensing operations since no calibration procedures are needed. Compared to similar sensing composites whose dopant are physically loaded, our SternVolmer curve is indeed improved by showing a better linearity [20,21]. Covalent grafting makes probe molecules uniformly distributed in supporting host, favoring linearity improvement.…”
Section: Sensing Mechanism and Stern-volmer Equationmentioning
“…This linear SternVolmer curve can indeed simplify sensing operations since no calibration procedures are needed. Compared to similar sensing composites whose dopant are physically loaded, our SternVolmer curve is indeed improved by showing a better linearity [20,21]. Covalent grafting makes probe molecules uniformly distributed in supporting host, favoring linearity improvement.…”
Section: Sensing Mechanism and Stern-volmer Equationmentioning
“…This may be due to the high electronic affinity of the oxadiazole moiety, which makes the phenyl group to be an electrondonating group. So the similar HOMO and LUMO energy levels of [Cu(bop)(PPh 3 …”
Section: Dft Calculationsmentioning
confidence: 78%
“…These data are consistent with the optical energy gaps, and the band gap trend is in good agreement with both the optical and electrochemical data. Due to the introduction of the CF 3 …”
Section: ) 2 ][Bf 4 ] and [Cu(pop)(pph 3 ) 2 ][Bf 4 ] Can Be Rationalmentioning
confidence: 99%
“…Luminescent metal complexes are key materials for modern technology, such as organic light-emitting diodes (OLEDs) [1], lightemitting electrochemical cells (LECs) [2], biological probing and oxygen-sensing [3]. In many cases, complexes based on some precious (i.e.…”
“…6. What's more, it can be expected that [Cu(P-P) (N-N)] þ complexes with a large coplanar conjugation diamine ligand may offer higher sensitivities, while, a small coplanar conjugation diamine ligand may compromise the sensitivity performance [17,23].…”
Section: Further Analysis On Oxygen Sensing Mechanism Of [Cu(pop) (Ecmentioning
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