“…Organic photoluminescence materials always show unique photophysical properties, such as room temperature phosphorescence (RTP) emission, [1][2][3] thermally activated delayed fluorescence (TADF), [4,5] triplet-triplet annihilation up-conversion photoluminescence (TTA-UCPL), [6,7] and so on. Benefited from these attractive performances, organic luminescence materials DOI: 10.1002/adom.202301601 have been widely applied in various fields, such as information encryption, [8][9][10] sensors, [11,12] bioimaging, [13,14] optoelectronic devices, [15,16] photo-catalysis, [17,18] etc. However, organic compounds usually exhibit inefficient intersystem crossing (ISC) processes because of their weak spin-orbit coupling (SOC).…”