“…The red shift observed may have implications for the applications of the composite material in the field of photocatalytic treatment of wastewater. The band gap energy is determined using Tauc’s equation, (αh) 2 = A(hυ − Eg) [ 6 , 15 ], where n is 2 for direct transition semiconductor and n is 1/2 for indirect transition semiconductor [ 8 , 18 ]. α is the absorption coefficient, h is the Planck constant, υ is the frequency, and A is the absorbance constant [ 15 , 18 ].…”
Section: Resultsmentioning
confidence: 99%
“…The band gap energy is determined using Tauc’s equation, (αh) 2 = A(hυ − Eg) [ 6 , 15 ], where n is 2 for direct transition semiconductor and n is 1/2 for indirect transition semiconductor [ 8 , 18 ]. α is the absorption coefficient, h is the Planck constant, υ is the frequency, and A is the absorbance constant [ 15 , 18 ]. By extending the line to (αh) 2 = 0, the band gap energies of Fe 3 O 4 /ZnO and ZnO are calculated as 2.47 and 3.23 eV, respectively.…”
Section: Resultsmentioning
confidence: 99%
“…Among various recalcitrant organic pollutants, organic dyes possess the properties of high chroma, huge water volume, toxicity, and low biodegradability, which makes it difficult to purify dye wastewater to a suitable level before releasing it into the environment [1,[8][9][10][11]. The photocatalytic oxidation method, physical coagulation method, Fenton oxidation method, and biodegradation method are now the most frequently used techniques for treating dye wastewater [2,[12][13][14][15][16]. Among these treatment techniques, the semiconductor-based photocatalytic oxidation approach offers the advantages of stability, non-toxicity, high Nanomaterials 2024, 14, 926 2 of 21 efficiency, low energy consumption, and environmentally friendly features, which has drawn a lot of interest from researchers [17][18][19][20].…”
Magnetic separation of photocatalysts holds great promise for water treatment. A magnetic separation method has a positive effect on the recovery of catalysts after degradation. In this paper, an efficient and reusable catalytic system is developed based on coating magnetic Fe3O4 by depositing Fe2+ on the surface of ZnO. The Fe3O4/ZnO nanocomposite exhibits enhanced performance for organic pollutant degradation. The Fe3O4/ZnO system demonstrates a high photocatalytic activity of 100% degradation efficiency in Rhodamine B (RhB) degradation under UV light irradiation for 50 min. The excellent photocatalytic activity is primarily due to the separation of photogenerated electron-hole pairs being facilitated by the strong interaction between Fe3O4 and ZnO. The induction of the magnetic Fe3O4 endows the Fe3O4/ZnO composite with superior magnetic separation capability from water. Experiments with different radical scavengers revealed that the hydroxyl radical (·OH) is the key reactive radical for the effective degradation of RhB. This work innovatively affords a common interfacial dopant deposition strategy for catalytic application in the degradation of organic dye pollutants and catalyst separation from wastewater efficiently.
“…The red shift observed may have implications for the applications of the composite material in the field of photocatalytic treatment of wastewater. The band gap energy is determined using Tauc’s equation, (αh) 2 = A(hυ − Eg) [ 6 , 15 ], where n is 2 for direct transition semiconductor and n is 1/2 for indirect transition semiconductor [ 8 , 18 ]. α is the absorption coefficient, h is the Planck constant, υ is the frequency, and A is the absorbance constant [ 15 , 18 ].…”
Section: Resultsmentioning
confidence: 99%
“…The band gap energy is determined using Tauc’s equation, (αh) 2 = A(hυ − Eg) [ 6 , 15 ], where n is 2 for direct transition semiconductor and n is 1/2 for indirect transition semiconductor [ 8 , 18 ]. α is the absorption coefficient, h is the Planck constant, υ is the frequency, and A is the absorbance constant [ 15 , 18 ]. By extending the line to (αh) 2 = 0, the band gap energies of Fe 3 O 4 /ZnO and ZnO are calculated as 2.47 and 3.23 eV, respectively.…”
Section: Resultsmentioning
confidence: 99%
“…Among various recalcitrant organic pollutants, organic dyes possess the properties of high chroma, huge water volume, toxicity, and low biodegradability, which makes it difficult to purify dye wastewater to a suitable level before releasing it into the environment [1,[8][9][10][11]. The photocatalytic oxidation method, physical coagulation method, Fenton oxidation method, and biodegradation method are now the most frequently used techniques for treating dye wastewater [2,[12][13][14][15][16]. Among these treatment techniques, the semiconductor-based photocatalytic oxidation approach offers the advantages of stability, non-toxicity, high Nanomaterials 2024, 14, 926 2 of 21 efficiency, low energy consumption, and environmentally friendly features, which has drawn a lot of interest from researchers [17][18][19][20].…”
Magnetic separation of photocatalysts holds great promise for water treatment. A magnetic separation method has a positive effect on the recovery of catalysts after degradation. In this paper, an efficient and reusable catalytic system is developed based on coating magnetic Fe3O4 by depositing Fe2+ on the surface of ZnO. The Fe3O4/ZnO nanocomposite exhibits enhanced performance for organic pollutant degradation. The Fe3O4/ZnO system demonstrates a high photocatalytic activity of 100% degradation efficiency in Rhodamine B (RhB) degradation under UV light irradiation for 50 min. The excellent photocatalytic activity is primarily due to the separation of photogenerated electron-hole pairs being facilitated by the strong interaction between Fe3O4 and ZnO. The induction of the magnetic Fe3O4 endows the Fe3O4/ZnO composite with superior magnetic separation capability from water. Experiments with different radical scavengers revealed that the hydroxyl radical (·OH) is the key reactive radical for the effective degradation of RhB. This work innovatively affords a common interfacial dopant deposition strategy for catalytic application in the degradation of organic dye pollutants and catalyst separation from wastewater efficiently.
“…3 However, its performance is limited by its ability to only absorb the UV light, which dissipates the abundance of solar light. 2,14 CdS photocatalysts that are sensitive to visible light have also been used, but their high charge recombination and toxic cadmium content make them less feasible for the photocatalytic reaction. 2,15 Due to the easy method for synthesis and a great physicochemical stability, graphitic carbon nitride (g-C 3 N 4 ) is widely used for photocatalytic processes.…”
The exploration of co-catalyst effects in photocatalytic H2 production along with biomass reforming is still limited. This study employs S- and N-doped graphene oxide dots (SNGODs) along with Pt and...
“…[12][13][14][15][16][17][18][19][20][21][22] As an n-type metal oxide semiconductor, SnO 2 has been extensively applied in photoelectrochemistry because of its advantages, such as high stability, non-toxicity, and cost-effectiveness. However, the use of SnO 2 as a single catalyst is not efficient enough due to the large bandgap and rapid charge recombination; 23 accordingly, many modication strategies such as doping, 24,25 morphology control, 26,27 and incorporation of a co-catalyst 28,29 have been devoted to further enhance the photocatalytic efficiency. Among these approaches, coupling with a plasmonic co-catalyst, typically silver (Ag), is benecial for not only expanding the light absorption range but also enhancing photogenerated charge separation.…”
The treatment or conversion of air pollutants with the low generation of secondary toxic substances becomes the hot spot in indoor air pollution abatement. Herein, we utilized triangle-shaped Ag coupled...
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