Chemical and mineralogical studies of the Davis Formation show that very fine grained authigenic potassium feldspar, a major silicate, formed diagenetically at the expense of detrital vitric volcanic ash deposited in a marine environment The chemistry, mineralogy, and texture of the Upper Cambrian Davis Formation are consistent with the concept that its silicate minerals originated chiefly from vitric volcanic ash that was deposited in a marine environment and then altered during diagenesis to potassium feldspar. Dolomite, calcite, illitesmectite, chlorite, and sparse glauconite and pyrite in the Davis also formed diagenetically. Quartz occurs in some beds and is largely detrital. Very fine grained authigenic monoclinic potassium feldspar is the dominant mineral in all insoluble residue samples and constitutes as much as 60 percent of many of the residues; only minor amounts of detrital igneous orthoclase and microcline (to 60 J.A.m) are recognized in polished grain mounts and thin sections. By contrast, the authigenic potassium feldspar crystals are so small (0.03-5 J.A.m) that they can be conclusively identified by scanning electron microscopy, electron-microprobe, or X-ray diffraction methods.
U.S. GEOLOGICAL SURVEY BULLETIN 1694 CONTRIBUTIONS TO MINERAL RESOURCES RESEARCH, 1984
CONTENTSThat the silicate minerals in the Davis Formation are authigenic is also suggested by the composition and distribution of nearby igneous rocks. The Davis is thickest in the region surrounding the core of Precambrian igneous rocks that now form the St. Francois Mountains. These Precambrian granites and rhyolites were also exposed during Davis deposition, yet they contributed only a minor local detrital component to the Davis Formation. Evidence for this conclusion includes (1) the very high K 2 0:Na 2 0 (weight percent) ratio of >55, and (2) K 2 0 contents of 10-11 percent for beds in the Davis; these values are large compared with those for the local Precambrian igneous rocks. In addition, the K 2 0, barium, zirconium, and boron concentrations for Davis samples differ significantly from the concentrations of these components in local Precambrian rocks. Further, the absence of quartz in some of the Davis samples, and the euhedral potassium feldspar grains smaller than 5 J.A.m, taken with the other evidence preceding, all suggest an authigenic origin for potassium feldspar in many beds in the Davis.The lower half of the marine Franconia Formation in Minnesota has been reported to contain nearly 50 percent authigenic potassium feldspar. These strata are age equivalent to the Davis Formation.
INTRODUCTIONIn the past several years, highly potassic strata in which potassium feldspar is the major potassium-bearing mineral and also the major silicate mineral have commonly been considered to have originated from the diagenetic alteration of volcanogenic or tuffaceous debris. This interpretation has been applied to both lacustrine (Sheppard and Gude, 1965) and marine (Weiss, 1954) occurrences. Buyce and Friedman (1975) have emphasiz...