2021
DOI: 10.26434/chemrxiv.14044205.v1
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A Revised Relationship Between Fracture Toughness and Y2O3 Content in Modern Dental Zirconias

Abstract: <p>The relationship between fracture toughness and Yttria content in modern zirconia ceramics was revised. For that purpose, we evaluated here 10 modern Y<sub>2</sub>O<sub>3</sub>-stabilized zirconia (YSZ) materials currently used in biomedical applications, namely prosthetic and implant dentistry. The most relevant range between 2-5 mol% Y<sub>2</sub>O<sub>3</sub> was addressed by selecting from conventional opaque 3 mol% YSZ up to more translucent composi… Show more

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Cited by 6 publications
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“…Zirconia material is outstandingly large in both flexural strength and hardness, as compared with other restorative materials. In addition, the fracture toughness values of 5Y decrease by about 50% from that of 3Y with the cubic phase content due to the increasing of yttria content (Figure 13) [33]. Fracture toughness largely depends on the stress-induced phase transformation as mentioned above and decreases with the content of cubic phase that do not generate this transformation.…”
Section: Hardness Flexural Strength and Fracture Toughnessmentioning
confidence: 85%
“…Zirconia material is outstandingly large in both flexural strength and hardness, as compared with other restorative materials. In addition, the fracture toughness values of 5Y decrease by about 50% from that of 3Y with the cubic phase content due to the increasing of yttria content (Figure 13) [33]. Fracture toughness largely depends on the stress-induced phase transformation as mentioned above and decreases with the content of cubic phase that do not generate this transformation.…”
Section: Hardness Flexural Strength and Fracture Toughnessmentioning
confidence: 85%
“…From a crystallographic viewpoint, the observed change in crystal phase composition upon the addition of Ga 2 O 3 is thought to have a negative effect on flexural strength. The high flexural strength and fracture toughness of yttria partially stabilized zirconia polycrystals are attributed to tetragonal→monoclinic stress-induced phase transformation; accordingly, the higher the content of low yttrium tetragonal phase with high tetragonality (i.e., the phase at the origin of stress-induced phase transformation), the higher flexural strength and fracture toughness [ 23 ]. XRD results showed that the addition of Ga 2 O 3 decreased the tetragonality and the content of the low yttrium tetragonal phase.…”
Section: Resultsmentioning
confidence: 99%
“…Rietveld refinement was carried out from the obtained diffraction pattern using a Rietan-FP [ 22 ]. Two tetragonal phases with different yttria concentrations were used as the initial structural model for the Rietveld refinement ( Table 4 ) as described in a previous report [ 23 ].…”
Section: Methodsmentioning
confidence: 99%
“…7). This intermediate phase (t″ phase) is a yttriumrich tetragonal phase, which is present in 5Y zirconia but does not contribute to strength enhancement because it does not undergo a stress-induced phase transition to monoclinic phase 15,16) . In other words, the cubic crystal has improved translucency because it has grown into larger grains.…”
Section: Microstructure and Firing Conditions Of Uhtzmentioning
confidence: 99%