2023
DOI: 10.3389/fchem.2022.960894
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A review on gasification and pyrolysis of waste plastics

Abstract: Gasification and pyrolysis are thermal processes for converting carbonaceous substances into tar, ash, coke, char, and gas. Pyrolysis produces products such as char, tar, and gas, while gasification transforms carbon-containing products (e.g., the products from pyrolysis) into a primarily gaseous product. The composition of the products and their relative quantities are highly dependent on the configuration of the overall process and on the input fuel. Although in gasification, pyrolysis processes also occur i… Show more

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Cited by 23 publications
(11 citation statements)
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“…The water used in the HTL process can serve different roles (solvent, catalyst, and reactant) and involves a series of hydrothermal cracking, hydrolysis, free radical reaction, nucleophilic substitution, and cyclization reactions. The products obtained are mostly liquid hydrocarbon oils, with a significant moisture content Table shows the major advantages and disadvantages of the three processes with plastic as a feedstock. …”
Section: Thermochemical Conversion Processesmentioning
confidence: 99%
“…The water used in the HTL process can serve different roles (solvent, catalyst, and reactant) and involves a series of hydrothermal cracking, hydrolysis, free radical reaction, nucleophilic substitution, and cyclization reactions. The products obtained are mostly liquid hydrocarbon oils, with a significant moisture content Table shows the major advantages and disadvantages of the three processes with plastic as a feedstock. …”
Section: Thermochemical Conversion Processesmentioning
confidence: 99%
“…44 Additionally, the complexity of recycling PVC is attributed to the presence of chlorine. 37 To compare the profitability and degree of circularity of the optimal technology, 20 different scenarios are considered for model validation and analysis, as represented in Figure 4. The baseline approach in this study involves energy recovery through the incineration of mixed plastic waste without any prior sorting or separations.…”
Section: Degree Of Circularity Calculations and Constraintsmentioning
confidence: 99%
“…While mechanical recycling remains the most prevalent way of recycling solid plastic waste, , it is typically limited to high-purity plastic waste, since the presence of contaminants and additives within the waste mixture will degrade the final quality of the recycled products. , More recently, thermochemical recycling has been touted as a prospective solution that can address certain shortcomings of mechanical recycling, while still providing environmental advantages over landfilling and incineration. Regardless of the thermochemical recycling technology (e.g., gasification or pyrolysis), the utilization of catalysts within these processes lowers the reaction temperature required to attain a similar degree of polymer deconstruction or product yields. Furthermore, catalysts, particularly ones with size-and-shape selectivity, i.e., zeolites, can also enable fine-tuning of the final product distribution and allow for higher selectivity to desired, high-value products.…”
Section: Introductionmentioning
confidence: 99%