Compared to conventional passenger cars, the hybrid and electric alternatives include electric motors and large batteries; the use of clean energy, reduced operation emissions, and decreasing purchase prices can represent solid reasons for their market adoption. The feasibility of the transition to electric cars is analyzed herein in terms of the costs, main pollutants, and energy consumption of compact to large-sized cars. In this regard, the proposed life cycle assessment methodology evaluates the pollution and energetic impacts of the current passenger car models with a weight varying from 1.6 to 1.8 tons, depending on the car type, for a complete life cycle. The life cycle emissions and energy consumption are also determined through simulation in order to validate the estimated values for the considered powertrains. This study has shown that a transition to current full-electric passenger cars, based on a European and United States energy mix, is not currently sustainable in terms of energy consumption. The complete life cycle values are similar for the tested conventional and full-electric passenger cars, ranging from 5 to 5.2 MJ/km. By comparison, the hybrid alternatives and full-electric cars based solely on renewable energy present lower energy consumption, ranging from 3.32 to 4.62 MJ/km. At the same time, the hybrid alternatives and conventional cars provide relevant benefits in life cycle costs: 20–25% lower than full-electric cars. In terms of life cycle emissions, the tested full-electric cars based on renewables show a noticeable reduction in greenhouse gases and in other relevant pollutants: 37% and 62%, respectively, lower than that of conventional cars.