A review of the occurrence of selected micropollutants and microorganisms in different raw and treated manure – Environmental risk due to antibiotics after application to soil

Ghirardini, Andrea; Grillini, Vittoria; Verlicchi, Paola

doi:10.1016/j.scitotenv.2019.136118

Cited by 120 publications

(58 citation statements)

References 143 publications

(112 reference statements)

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“…While the OTC in Honghu, China, had a maximum concentration of 2796.6 ng L −1 [ 9 ]. In addition, the comparisons in animal excrement data showed that OTC was consistently the highest average compound [ 10 ]. Even more worryingly, antibiotic resistance genes caused by overuse of antibiotics can be transferred between environmental bacteria and human pathogens [ 11 ].…”

Section: Introductionmentioning

confidence: 99%

Green Preparation of Fluorescent Nitrogen-Doped Carbon Quantum Dots for Sensitive Detection of Oxytetracycline in Environmental Samples

Gao

Wang

et al. 2020

Nanomaterials

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Nitrogen-doped carbon quantum dots (N-CQDs) with strong fluorescence were prepared by a one-step hydrothermal method using natural biomass waste. Two efficient fluorescent probes were constructed for selective and sensitive detection of oxytetracycline (OTC). The synthesized N-CQDs were characterized by UV-visible absorption spectra, fluorescence spectra, Fourier transform infrared spectroscopy (FT-IR), X-ray photon spectroscopy (XPS), atomic force microscopy (AFM), and high-resolution transmission electron microscopy (HRTEM), which proved that the synthesized N-CQDs surface were functionalized and had stable fluorescence performance. The basis of N-CQDs detection of OTC was discussed, and various reaction conditions were studied. Under optimized conditions, orange peel carbon quantum dots (ON-CQDs) and watermelon peel carbon quantum dots (WN-CQDs) have a good linear relationship with OTC concentrations in the range of 2–100 µmol L−1 and 0.25–100 µmol L−1, respectively. ON-CQDs and WN-CQDs were both successfully applied in detecting the OTC in pretreated tap water, lake water, and soil, with the recovery rate at 91.724–103.206%, and the relative standard deviation was less than 5.35%. The results showed that the proposed N-CQDs proved to be green and simple, greatly reducing the detection time for OTC in the determination environment.

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Section: Introductionmentioning

confidence: 99%

Green Preparation of Fluorescent Nitrogen-Doped Carbon Quantum Dots for Sensitive Detection of Oxytetracycline in Environmental Samples

Gao

Wang

et al. 2020

Nanomaterials

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“…2 Furthermore, SMZ and its metabolites are known to enter water and soil samples through animal urine and feces, thus and posing a significant threat to the environment. 3,4 For instance, SMZ was detected in water samples collected from 60 agricultural regions in northern Spain. 5 Since environmental SMZ can enter the food chain through aquatic organisms and crops, and it is known that the SMZ can cause severe allergic reactions and thyroid tumors in humans, 6 it is essential to develop a rapid and sensitive method to detect SMZ in environmental samples.…”

Section: Introductionmentioning

confidence: 99%

An Ultrasensitive Label-Free Fluorescent Aptasensor Platform for Detection of Sulfamethazine

Wang¹,

Yan²,

Kou³

et al. 2021

IJN

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Purpose: Sulfamethazine (SMZ) exposed in the environment can enter the human body through the food chain and pose a serious threat to human health. Therefore, it is important to develop a rapid and sensitive method for detecting SMZ in environmental samples. In order to fastly and quantitatively detect SMZ in environmental samples, we developed a label-free fluorescent aptasensor based on specific aptamer (SMZ1S) and fluorescence resonance energy transfer (FRET) between gold nanoparticles (AuNPs) and rhodamine B (RhoB). Methods: In the absence of SMZ, SMZ1S was adsorbed on the surface of AuNPs, which led to dispersion of the AuNPs in high concentration saline solution, thus effectively quenching the fluorescence of RhoB. With the increase of the SMZ concentration, the specific binding of SMZ1S and SMZ led to the aggregation of AuNPs in the presence of NaCl, which reduced the quenching of RhoB fluorescence and increased the fluorescence intensity. The sensitivity and linearity curve of the label-free fluorescent aptasensor were determined with different concentrations of sulfamethazine standard solutions. The specificity of this fluorescent aptasensor was determined by replacing sulfamethazine with different antibiotics. In addition, the actual water and soil samples were spiked and recovered. Results: Under optimized conditions, the proposed fluorescent aptasensor demonstrated a good linear detection of SMZ in binding buffer from 1.25 ng mL −1 to 40 ng mL −1 and the limit of detection was 0.82 ng mL −1 . The spiked recoveries for SMZ were 94.4% to 108.8% with a relative standard deviation of 1.8-10.3% in water and soil samples, respectively. Conclusion:The label-free fluorescent aptasensor investigated in the current study is a promising tool to detect and quantify SMZ in water and soil samples.

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“…Antibiotics (ABs) are one of the most known chemical compounds that are extensively used for humans and animals to their prevention from microbial or infectious diseases [1]. Some studies showed that in a 5‐year period (between 2000 and 2015), ABs usage increased nearly to 42 billion doses in a year with the consumption rate of 39% [2].…”

Section: Introductionmentioning

confidence: 99%

“…Antibiotics (ABs) are one of the most known chemical compounds that are extensively used for humans and Article Related Abbreviations: AB, antibiotic; DES, deep eutectic solvent; DLLME, dispersive liquid-liquid microextraction; EF, enrichment factor; ER, extraction recovery; FA, Formaldehyde; IMS, ion mobility spectrometry; MWCNT, multiwall carbon nanotube; Ur, urea animals to their prevention from microbial or infectious diseases [1]. Some studies showed that in a 5-year period (between 2000 and 2015), ABs usage increased nearly to 42 billion doses in a year with the consumption rate of 39% [2].…”

Section: Introductionmentioning

confidence: 99%

Preparation of multiwall carbon nanotube/urea‐formaldehyde nanocomposite as a new sorbent in solid‐phase extraction and its combination with deep eutectic solvent‐based dispersive liquid–liquid microextraction for extraction of antibiotic residues in honey

Shahi

Javadi

Mogaddam

et al. 2020

J of Separation Science

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A solid‐phase extraction method combined with deep eutectic solvent‐based dispersive liquid–liquid microextraction has been developed for the extraction of three antibiotics in honey samples prior to their determination by ion mobility spectrometry. In this method, first, a multiwall carbon nanotube/urea‐formaldehyde nanocomposite was synthesized using co‐precipitation polymerization method and then it was used as a sorbent for the analytes extraction from the samples. After that the adsorbed analytes were eluted from the sorbent using a water‐miscible organic solvent. The collected elution solvent was mixed with tetrabutylammonium chloride:butanol deep eutectic solvent and the mixture was applied in the following microextraction method. The method provided low limits of detection and quantification in the ranges of 0.32–0.86 and 1.1–2.9 ng/g, respectively. The method had a proper repeatability expressed as relative standard deviation less than or equal to 9.1%. The validated method was successfully performed on different honey samples obtained from different producers.

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A review of the occurrence of selected micropollutants and microorganisms in different raw and treated manure – Environmental risk due to antibiotics after application to soil

Cited by 120 publications

References 143 publications

Green Preparation of Fluorescent Nitrogen-Doped Carbon Quantum Dots for Sensitive Detection of Oxytetracycline in Environmental Samples

Green Preparation of Fluorescent Nitrogen-Doped Carbon Quantum Dots for Sensitive Detection of Oxytetracycline in Environmental Samples

An Ultrasensitive Label-Free Fluorescent Aptasensor Platform for Detection of Sulfamethazine

Preparation of multiwall carbon nanotube/urea‐formaldehyde nanocomposite as a new sorbent in solid‐phase extraction and its combination with deep eutectic solvent‐based dispersive liquid–liquid microextraction for extraction of antibiotic residues in honey

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