Abstract:The excessive consumption of fossil fuels has caused severe energy shortage, and the large amount of CO2 released during the combustion process has broken the carbon balance in nature. Achieving...
“…Semiconductors, such as CdS, TiO 2 , and g-C 3 N 4 , are highly efficient and durable in catalyzing a wide range of photochemical and photoelectrochemical reactions. − Besides optimization of the crystal structure, particle size, and specific surface area of the semiconductors, exploring proper candidates to support these semiconductors can not only effectively improve the utilization efficiency by optimizing the dispersion state but also lead to synergistic effects, such as adsorption, photothermal, conductivity, and redox effects, which are unavailable on single-component catalysts. − Moreover, the support material may also modify the intrinsic properties of the semiconductor by the strong semiconductor–support interactions or creating active sites at the contact interface. − As a result, the overall photocatalytic activity of the hybrid material was greatly enhanced.…”
Polydopamine (PDA) is an excellent
polymer with abundant chemical
properties, such as broadband light absorption, surface redox activities,
hydrophilic surface, chemical coupling, and adsorption capacities
toward cation molecules/ions. Herein, we synthesized the PDA/CdS hybrid
material by employing PDA nanoparticles as the substrate via hydrothermal
reactions at various temperatures. Results indicate that the chelation
between Cd2+ ions and the PDA substrate can facilitate
the heterogeneous nucleation of CdS nanoparticles to obtain the uniform
dispersion status on the PDA surface. PDA/CdS was then employed to
study the photocatalytic–adsorption activities in removing
rhodamine B (RhB), where CdS and PDA primary served as the photocatalyst
and adsorption matrix, respectively, under xenon lamp irradiation.
The capacity of PDA nanoparticles toward RhB adsorption is reduced
along with the increased hydrothermal temperature because of an elevated
carbonization degree, while the photocatalytic activity and resistance
to photocorrosion of CdS nanoparticles are improved. The synergistic
effect between photocatalysis and adsorption is significant for RhB
removal. Finally, we demonstrate that the extremely complex surface
chemical properties of PDA can infer the photocatalytic–adsorption
behavior of PDA/CdS greatly by the experiments with sacrificial agents
and the pre-illumination process.
“…Semiconductors, such as CdS, TiO 2 , and g-C 3 N 4 , are highly efficient and durable in catalyzing a wide range of photochemical and photoelectrochemical reactions. − Besides optimization of the crystal structure, particle size, and specific surface area of the semiconductors, exploring proper candidates to support these semiconductors can not only effectively improve the utilization efficiency by optimizing the dispersion state but also lead to synergistic effects, such as adsorption, photothermal, conductivity, and redox effects, which are unavailable on single-component catalysts. − Moreover, the support material may also modify the intrinsic properties of the semiconductor by the strong semiconductor–support interactions or creating active sites at the contact interface. − As a result, the overall photocatalytic activity of the hybrid material was greatly enhanced.…”
Polydopamine (PDA) is an excellent
polymer with abundant chemical
properties, such as broadband light absorption, surface redox activities,
hydrophilic surface, chemical coupling, and adsorption capacities
toward cation molecules/ions. Herein, we synthesized the PDA/CdS hybrid
material by employing PDA nanoparticles as the substrate via hydrothermal
reactions at various temperatures. Results indicate that the chelation
between Cd2+ ions and the PDA substrate can facilitate
the heterogeneous nucleation of CdS nanoparticles to obtain the uniform
dispersion status on the PDA surface. PDA/CdS was then employed to
study the photocatalytic–adsorption activities in removing
rhodamine B (RhB), where CdS and PDA primary served as the photocatalyst
and adsorption matrix, respectively, under xenon lamp irradiation.
The capacity of PDA nanoparticles toward RhB adsorption is reduced
along with the increased hydrothermal temperature because of an elevated
carbonization degree, while the photocatalytic activity and resistance
to photocorrosion of CdS nanoparticles are improved. The synergistic
effect between photocatalysis and adsorption is significant for RhB
removal. Finally, we demonstrate that the extremely complex surface
chemical properties of PDA can infer the photocatalytic–adsorption
behavior of PDA/CdS greatly by the experiments with sacrificial agents
and the pre-illumination process.
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