2023
DOI: 10.1063/5.0111591
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A review of electrochemical glucose sensing based on transition metal phosphides

Abstract: The alarming situation of the growing number of diabetic patients has called for a simple, sensitive, and selective glucose sensor that is also stable and user-friendly. In this report, we have reviewed the latest electrochemical sensing technology based on transition metal phosphides (TMPs) for glucose detection. Apart from the oxides, sulfides, nitrides, chalcogenides, etc., transition metal phosphides are less explored and have emerged as potential candidates for non-enzymatic glucose sensing applications. … Show more

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Cited by 6 publications
(4 citation statements)
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“…A survey of the literature revealed that EC sensors were increasingly built using 2D materials that included graphene-based materials, transition metal dichalcogenides (TMDCs), black phosphorous (BP), hexagonal boron nitride (h-BN), metal-oxides (MO), metalorganic frameworks (MOFs), 2D carbides and nitrides of transition metals (MXenes). 18,24,28,[32][33][34][35][36] Their unique physicochemical properties are to be exploited and employed in fabricating EC sensors for enhanced selectivity and sensitivity. Modern EC sensors utilize various features to determine the physical, chemical, and biological aspects of day-to-day life.…”
Section: The Necessity Of Working Electrode Surface Modificationmentioning
confidence: 99%
“…A survey of the literature revealed that EC sensors were increasingly built using 2D materials that included graphene-based materials, transition metal dichalcogenides (TMDCs), black phosphorous (BP), hexagonal boron nitride (h-BN), metal-oxides (MO), metalorganic frameworks (MOFs), 2D carbides and nitrides of transition metals (MXenes). 18,24,28,[32][33][34][35][36] Their unique physicochemical properties are to be exploited and employed in fabricating EC sensors for enhanced selectivity and sensitivity. Modern EC sensors utilize various features to determine the physical, chemical, and biological aspects of day-to-day life.…”
Section: The Necessity Of Working Electrode Surface Modificationmentioning
confidence: 99%
“…To mitigate periodic interactions, a 30 Å vacuum layer was added above the surface of the layer within the extended cell [58]. Furthermore, Grimme's DFT-D3 correction scheme was implemented to address van der Waals (vdW) interactions between the single layer and the gas molecule [59,60].…”
Section: Computational Particularsmentioning
confidence: 99%
“…Transition metal phosphides with nearly metallic properties have shown outstanding electrical conductivity in electrochemical sensing. 10,11 Moreover, by coupling them with an Ndoped porous carbon matrix, the different electronegativities of P, C, and N elements offer various possibilities to tailor the electronic structure of the material, thereby tuning the electrocatalytic performance. 12,13 Metal-organic frameworks (MOFs) with tunable compositions have recently proved an excellent template to synthesize heteroatom-doped porous carbon-based materials for electrochemical catalysis.…”
Section: Introductionmentioning
confidence: 99%